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Carbon monoxide, dinitrogen and carbon dioxide adsorption on zeolite H-Beta: IR spectroscopic and thermodynamic studies

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  • Delgado, Montserrat Rodriguez
  • Arean, Carlos Otero

Abstract

Variable temperature IR spectroscopy (VTIR) was used to investigate the adsorption thermodynamics of carbon monoxide, dinitrogen and carbon dioxide on the protonic zeolite H-Beta. Interaction of the adsorbed gases with the zeolite Brønsted acid sites was found to involve an enthalpy change of −27, −19 and −33 kJ mol−1 for CO, N2 and CO2, respectively; the corresponding entropy change was −150, −140 and −146 J mol−1 K−1. The adsorbed gases showed also a weak interaction with silanols, which involves a ΔH0 value in the approximate range of −7 to −10 kJ mol−1. These results were discussed in the context of gas separation and carbon capture and sequestration (CCS) using zeolites.

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  • Delgado, Montserrat Rodriguez & Arean, Carlos Otero, 2011. "Carbon monoxide, dinitrogen and carbon dioxide adsorption on zeolite H-Beta: IR spectroscopic and thermodynamic studies," Energy, Elsevier, vol. 36(8), pages 5286-5291.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:8:p:5286-5291
    DOI: 10.1016/j.energy.2011.06.033
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    1. Mofarahi, Masoud & Khojasteh, Yaser & Khaledi, Hiwa & Farahnak, Arsalan, 2008. "Design of CO2 absorption plant for recovery of CO2 from flue gases of gas turbine," Energy, Elsevier, vol. 33(8), pages 1311-1319.
    2. Olajire, Abass A., 2010. "CO2 capture and separation technologies for end-of-pipe applications – A review," Energy, Elsevier, vol. 35(6), pages 2610-2628.
    3. Park, Kyungtae & Shin, Dongil & Yoon, En Sup, 2011. "The cost of energy analysis and energy planning for emerging, fossil fuel power plants based on the climate change scenarios," Energy, Elsevier, vol. 36(5), pages 3606-3612.
    4. Emberley, S. & Hutcheon, I. & Shevalier, M. & Durocher, K. & Gunter, W.D. & Perkins, E.H., 2004. "Geochemical monitoring of fluid-rock interaction and CO2 storage at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada," Energy, Elsevier, vol. 29(9), pages 1393-1401.
    5. Montanari, Tania & Finocchio, Elisabetta & Salvatore, Enrico & Garuti, Gilberto & Giordano, Andrea & Pistarino, Chiara & Busca, Guido, 2011. "CO2 separation and landfill biogas upgrading: A comparison of 4A and 13X zeolite adsorbents," Energy, Elsevier, vol. 36(1), pages 314-319.
    6. Pellegrini, G. & Strube, R. & Manfrida, G., 2010. "Comparative study of chemical absorbents in postcombustion CO2 capture," Energy, Elsevier, vol. 35(2), pages 851-857.
    7. Davison, John, 2007. "Performance and costs of power plants with capture and storage of CO2," Energy, Elsevier, vol. 32(7), pages 1163-1176.
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