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Exergy recovery from steelmaking off-gas by latent heat storage for methanol production

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  • Maruoka, Nobuhiro
  • Akiyama, Tomohiro

Abstract

This paper proposes a new thermal energy recovery process of hot gas exhausted from the steelmaking converter by utilizing not only latent heat but also endothermic heat of reaction. The intermittently emitted LD gas was first transferred into continuous, constant-temperature heat source in the form of latent heat in the Phase Change Material (PCM) of copper. Then, the stored heat was supplied to Coke Oven Gas (COG) to induce endothermic reaction of steam reforming of methane. Methanol was finally produced from the obtained gas in the proposed system. A heat and material balance model predicted all operating data of the system and then exergy analysis based on the predicted data was conducted to validate the system theoretically. The results showed that the proposed system has a possibility to produce a large amount of methanol corresponding to 20% of total demand in Japan, with only 28% of exergy consumption in the conventional method.

Suggested Citation

  • Maruoka, Nobuhiro & Akiyama, Tomohiro, 2006. "Exergy recovery from steelmaking off-gas by latent heat storage for methanol production," Energy, Elsevier, vol. 31(10), pages 1632-1642.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:10:p:1632-1642
    DOI: 10.1016/j.energy.2005.05.023
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    1. Uribe-Soto, Wilmar & Portha, Jean-François & Commenge, Jean-Marc & Falk, Laurent, 2017. "A review of thermochemical processes and technologies to use steelworks off-gases," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 809-823.
    2. Matino, Ismael & Dettori, Stefano & Colla, Valentina & Weber, Valentine & Salame, Sahar, 2019. "Forecasting blast furnace gas production and demand through echo state neural network-based models: Pave the way to off-gas optimized management," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    3. Miró, Laia & Gasia, Jaume & Cabeza, Luisa F., 2016. "Thermal energy storage (TES) for industrial waste heat (IWH) recovery: A review," Applied Energy, Elsevier, vol. 179(C), pages 284-301.
    4. Fukahori, Ryo & Nomura, Takahiro & Zhu, Chunyu & Sheng, Nan & Okinaka, Noriyuki & Akiyama, Tomohiro, 2016. "Thermal analysis of Al–Si alloys as high-temperature phase-change material and their corrosion properties with ceramic materials," Applied Energy, Elsevier, vol. 163(C), pages 1-8.
    5. Fukahori, Ryo & Nomura, Takahiro & Zhu, Chunyu & Sheng, Nan & Okinaka, Noriyuki & Akiyama, Tomohiro, 2016. "Macro-encapsulation of metallic phase change material using cylindrical-type ceramic containers for high-temperature thermal energy storage," Applied Energy, Elsevier, vol. 170(C), pages 324-328.
    6. Shin, Sunkyu & Lee, Jeong-Keun & Lee, In-Beum, 2020. "Development and techno-economic study of methanol production from coke-oven gas blended with Linz Donawitz gas," Energy, Elsevier, vol. 200(C).
    7. Ji, Chenzhen & Qin, Zhen & Dubey, Swapnil & Choo, Fook Hoong & Duan, Fei, 2017. "Three-dimensional transient numerical study on latent heat thermal storage for waste heat recovery from a low temperature gas flow," Applied Energy, Elsevier, vol. 205(C), pages 1-12.
    8. Kang, Dongseong & Byun, Jaewon & Han, Jee-hoon, 2023. "Environmental impact analysis of steelmaking off-gases on methanol production," Energy, Elsevier, vol. 277(C).
    9. Wu, Chang-Bo & Wu, Gang & Yang, Xi & Liu, Yu-Jing & Liang, Tao & Fu, Wei-Fei & Wang, Mang & Chen, Hong-Zheng, 2015. "Preparation of microencapsulated medium temperature phase change material of Tris(hydroxymethyl)methyl aminomethane@SiO2 with excellent cycling performance," Applied Energy, Elsevier, vol. 154(C), pages 361-368.
    10. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    11. Han, Pengju & Lu, Lixin & Qiu, Xiaolin & Tang, Yali & Wang, Jun, 2015. "Preparation and characterization of macrocapsules containing microencapsulated PCMs (phase change materials) for thermal energy storage," Energy, Elsevier, vol. 91(C), pages 531-539.
    12. Song, Weiming & Zhou, Jianan & Li, Yujie & Yang, Jian & Cheng, Rijin, 2021. "New technology for producing high-quality combustible gas by high-temperature reaction of dust-removal coke powder in mixed atmosphere," Energy, Elsevier, vol. 233(C).
    13. Kawaguchi, Takahiro & Sakai, Hiroki & Sheng, Nan & Kurniawan, Ade & Nomura, Takahiro, 2020. "Microencapsulation of Zn-Al alloy as a new phase change material for middle-high-temperature thermal energy storage applications," Applied Energy, Elsevier, vol. 276(C).
    14. Li, Zhi & Lu, Yiji & Huang, Rui & Chang, Jinwei & Yu, Xiaonan & Jiang, Ruicheng & Yu, Xiaoli & Roskilly, Anthony Paul, 2021. "Applications and technological challenges for heat recovery, storage and utilisation with latent thermal energy storage," Applied Energy, Elsevier, vol. 283(C).
    15. Nomura, Takahiro & Sheng, Nan & Zhu, Chunyu & Saito, Genki & Hanzaki, Daiki & Hiraki, Takehito & Akiyama, Tomohiro, 2017. "Microencapsulated phase change materials with high heat capacity and high cyclic durability for high-temperature thermal energy storage and transportation," Applied Energy, Elsevier, vol. 188(C), pages 9-18.
    16. Zhang, Lijun & Chennells, Michael & Xia, Xiaohua, 2018. "A power dispatch model for a ferrochrome plant heat recovery cogeneration system," Applied Energy, Elsevier, vol. 227(C), pages 180-189.
    17. Nomura, Takahiro & Tabuchi, Kazuki & Zhu, Chunyu & Sheng, Nan & Wang, Shuangfeng & Akiyama, Tomohiro, 2015. "High thermal conductivity phase change composite with percolating carbon fiber network," Applied Energy, Elsevier, vol. 154(C), pages 678-685.
    18. Jia, Jie & Lee, W.L., 2015. "Experimental investigations on using phase change material for performance improvement of storage-enhanced heat recovery room air-conditioner," Energy, Elsevier, vol. 93(P2), pages 1394-1403.
    19. Xu, Ben & Li, Peiwen & Chan, Cholik, 2015. "Application of phase change materials for thermal energy storage in concentrated solar thermal power plants: A review to recent developments," Applied Energy, Elsevier, vol. 160(C), pages 286-307.
    20. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    21. Xia, Mingzhu & Yuan, Yanping & Zhao, Xudong & Cao, Xiaoling & Tang, Zhonghua, 2016. "Cold storage condensation heat recovery system with a novel composite phase change material," Applied Energy, Elsevier, vol. 175(C), pages 259-268.
    22. Maruoka, Nobuhiro & Tsutsumi, Taichi & Ito, Akihisa & Hayasaka, Miho & Nogami, Hiroshi, 2020. "Heat release characteristics of a latent heat storage heat exchanger by scraping the solidified phase change material layer," Energy, Elsevier, vol. 205(C).
    23. Khoa, T.D. & Shuhaimi, M. & Hashim, H. & Panjeshahi, M.H., 2010. "Optimal design of distillation column using three dimensional exergy analysis curves," Energy, Elsevier, vol. 35(12), pages 5309-5319.
    24. Nomura, Takahiro & Zhu, Chunyu & Nan, Sheng & Tabuchi, Kazuki & Wang, Shuangfeng & Akiyama, Tomohiro, 2016. "High thermal conductivity phase change composite with a metal-stabilized carbon-fiber network," Applied Energy, Elsevier, vol. 179(C), pages 1-6.

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