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Kinetic study on the CO2 gasification of biochar derived from Miscanthus at different processing conditions

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  • Tian, Hong
  • Hu, Qingsong
  • Wang, Jiawei
  • Chen, Donglin
  • Yang, Yang
  • Bridgwater, Anthony V.

Abstract

The CO2 gasification is an emerging process that can improve the quality of syngas and enhance the CO2 circular utilisation. This paper presents a comprehensive analysis on the CO2 gasification of Miscanthus-derived biochar produced at varying processing conditions. The gasification behaviour, kinetics and biochar reactivity were investigated and the correlations to the biochar preparation conditions and their microstructure were developed. Results showed that the preparation and gasification reaction conditions had major impact on the biochar reactivity. The order of significance that affected the biochar reactivity was gasification temperature, biochar preparation temperature and processing atmosphere. Increasing heating rate could enhance the biochar reactivity, while increasing preparation temperature could reduce the reactivity in N2 and He atmosphere. At 600 and 1000 °C, He atmosphere resulted in the most activity biochar, followed by N2 and CO2. At 800 °C, CO2 atmosphere gave the highest reactivity, followed by He and N2. The Activation Energy (E) of gasification reaction calculated by the Hybrid Model (HM) was mainly in the range of 78.09–212.46 kJ mol−1. The E decreased with the increase of carbon conversion rate. A great kinetic compensation effect between E and A was identified during the CO2 gasification process.

Suggested Citation

  • Tian, Hong & Hu, Qingsong & Wang, Jiawei & Chen, Donglin & Yang, Yang & Bridgwater, Anthony V., 2021. "Kinetic study on the CO2 gasification of biochar derived from Miscanthus at different processing conditions," Energy, Elsevier, vol. 217(C).
    • Handle: RePEc:eee:energy:v:217:y:2021:i:c:s0360544220324488
    DOI: 10.1016/j.energy.2020.119341
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    1. Lin, Leteng & Strand, Michael, 2013. "Investigation of the intrinsic CO2 gasification kinetics of biomass char at medium to high temperatures," Applied Energy, Elsevier, vol. 109(C), pages 220-228.
    2. Fatehi, Hesameddin & Bai, Xue-Song, 2017. "Structural evolution of biomass char and its effect on the gasification rate," Applied Energy, Elsevier, vol. 185(P2), pages 998-1006.
    3. Hu, Qiang & Yang, Haiping & Wu, Zhiqiang & Lim, C. Jim & Bi, Xiaotao T. & Chen, Hanping, 2019. "Experimental and modeling study of potassium catalyzed gasification of woody char pellet with CO2," Energy, Elsevier, vol. 171(C), pages 678-688.
    4. Wang, Guangwei & Zhang, Jianliang & Chang, Weiwei & Li, Rongpeng & Li, Yanjiang & Wang, Chuan, 2018. "Structural features and gasification reactivity of biomass chars pyrolyzed in different atmospheres at high temperature," Energy, Elsevier, vol. 147(C), pages 25-35.
    5. Vincent, Shubha Shalini & Mahinpey, Nader & Aqsha, Aqsha, 2014. "Mass transfer studies during CO2 gasification of torrefied and pyrolyzed chars," Energy, Elsevier, vol. 67(C), pages 319-327.
    6. Wu, Zhiqiang & Yang, Wangcai & Meng, Haiyu & Zhao, Jun & Chen, Lin & Luo, Zhengyuan & Wang, Shuzhong, 2017. "Physicochemical structure and gasification reactivity of co-pyrolysis char from two kinds of coal blended with lignocellulosic biomass: Effects of the carboxymethylcellulose sodium," Applied Energy, Elsevier, vol. 207(C), pages 96-106.
    7. Wang, Guangwei & Zhang, Jianliang & Shao, Jiugang & Liu, Zhengjian & Wang, Haiyang & Li, Xinyu & Zhang, Pengcheng & Geng, Weiwei & Zhang, Guohua, 2016. "Experimental and modeling studies on CO2 gasification of biomass chars," Energy, Elsevier, vol. 114(C), pages 143-154.
    8. Zhai, Ming & Liu, Jianing & Wang, Ze & Guo, Li & Wang, Xinyu & Zhang, Yu & Dong, Peng & Sun, Jiawei, 2017. "Gasification characteristics of sawdust char at a high-temperature steam atmosphere," Energy, Elsevier, vol. 128(C), pages 509-518.
    9. Sonibare, Oluwadayo O. & Haeger, Tobias & Foley, Stephen F., 2010. "Structural characterization of Nigerian coals by X-ray diffraction, Raman and FTIR spectroscopy," Energy, Elsevier, vol. 35(12), pages 5347-5353.
    10. Gil, María V. & Riaza, Juan & Álvarez, Lucía & Pevida, Covadonga & Rubiera, Fernando, 2015. "Biomass devolatilization at high temperature under N2 and CO2: Char morphology and reactivity," Energy, Elsevier, vol. 91(C), pages 655-662.
    11. Kibria, M.A. & Sripada, Pramod & Bhattacharya, Sankar, 2020. "Steady state kinetic model for entrained flow CO2 gasification of biomass at high temperature," Energy, Elsevier, vol. 196(C).
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    4. Zhou, Yufang & Gao, Mingqiang & Miao, Zhenyong & Cheng, Cheng & Wan, Keji & He, Qiongqiong, 2024. "Physicochemical properties and combustion kinetics of dried lignite," Energy, Elsevier, vol. 289(C).
    5. Wang, Yu & Ge, Zhiwei & Shang, Fei & Zhou, Chenchen & Guo, Shenghui & Ren, Changyifan, 2023. "Kinetic analysis of CO2 gasification of corn straw," Renewable Energy, Elsevier, vol. 203(C), pages 219-227.

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