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Behaviors of methane hydrate formation and growth with halo

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  • Liu, Qingbin
  • Li, Shaohua
  • Jiang, Lanlan
  • Yang, Mingjun
  • Yu, Tao
  • Song, Yongchen

Abstract

Gas production efficiency is closely linked to the formation and growth of pore-scale methane hydrates (MH). This study presents a novel high-pressure micromodel equipped with a high-resolution CCD camera to observe MH morphology in situ, revealing the dynamic mechanisms during MH formation via diffusion. We describe the growth evolution of hydrate halos under static conditions and the influence of temperature. Halos grow from the interface to the gas phase, increasing the contact area between hydrate and grains. The halo's complexity, characterized by the fractal dimension, increased from 1.489 to 1.753 as it developed. Small droplets supplied water for halo growth through vapor pressure gradients. A dimensionless parameter H⁎ was introduced to indicate the potential contact between hydrate halos and liquid droplets, with a critical value of 1. The halo profile became more complex over time and with decreasing temperature. Halos slow hydrate decomposition and pose challenges for exploitation. Numerous small hydrate shell fragments formed under gas-water flow, enhancing gas-to-hydrate conversion rates. This study elucidates the kinetic growth mechanisms of hydrate halos under water vapor diffusion, offering valuable insights into MH storage in subsurface environments and providing crucial reference for their exploitation.

Suggested Citation

  • Liu, Qingbin & Li, Shaohua & Jiang, Lanlan & Yang, Mingjun & Yu, Tao & Song, Yongchen, 2025. "Behaviors of methane hydrate formation and growth with halo," Applied Energy, Elsevier, vol. 381(C).
  • Handle: RePEc:eee:appene:v:381:y:2025:i:c:s0306261924025157
    DOI: 10.1016/j.apenergy.2024.125131
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    References listed on IDEAS

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    1. Wang, Bin & Dong, Hongsheng & Liu, Yanzhen & Lv, Xin & Liu, Yu & Zhao, Jiafei & Song, Yongchen, 2018. "Evaluation of thermal stimulation on gas production from depressurized methane hydrate deposits☆," Applied Energy, Elsevier, vol. 227(C), pages 710-718.
    2. Chong, Zheng Rong & Yin, Zhenyuan & Tan, Jun Hao Clifton & Linga, Praveen, 2017. "Experimental investigations on energy recovery from water-saturated hydrate bearing sediments via depressurization approach," Applied Energy, Elsevier, vol. 204(C), pages 1513-1525.
    3. Lee, Yohan & Deusner, Christian & Kossel, Elke & Choi, Wonjung & Seo, Yongwon & Haeckel, Matthias, 2020. "Influence of CH4 hydrate exploitation using depressurization and replacement methods on mechanical strength of hydrate-bearing sediment," Applied Energy, Elsevier, vol. 277(C).
    4. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    5. Dyhia Atig & Daniel Broseta & Jean-Michel Pereira & Ross Brown, 2020. "Contactless probing of polycrystalline methane hydrate at pore scale suggests weaker tensile properties than thought," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    6. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    7. Xu, Huazheng & Liu, Yingying & He, Siyuan & Zheng, Jia-nan & Jiang, Lanlan & Song, Yongchen, 2024. "Enhanced CO2 hydrate formation using hydrogen-rich stones, L-Methionine and SDS: Insights from kinetic and morphological studies," Energy, Elsevier, vol. 291(C).
    8. Chong, Zheng Rong & Pujar, Girish Anand & Yang, Mingjun & Linga, Praveen, 2016. "Methane hydrate formation in excess water simulating marine locations and the impact of thermal stimulation on energy recovery," Applied Energy, Elsevier, vol. 177(C), pages 409-421.
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