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Energy efficient diethylenetriamine–1-propanol biphasic solvent for CO2 capture: Experimental and theoretical study

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  • Wang, Rujie
  • Yang, Yuying
  • Wang, Mengfan
  • Lin, Jinshan
  • Zhang, Shihan
  • An, Shanlong
  • Wang, Lidong

Abstract

Biphasic solvents characterized by a substantially decreased regeneration heat consumption are promising alternative CO2 absorbents to typical monoethanolamine (MEA). In this study, 1-propanol was used as a phase splitter for diethylenetriamine (DETA) aqueous solvents. A tunable phase separation property was achieved by simply varying the concentration of 1-propanol. The 30 wt% DETA–50 wt% 1-propanol solvent exhibited the best phase separation properties with a volume ratio (rich–phase) of 41.7% and a rich loading of 6.54 mol/L. A molecular scale understanding of the phase separation mechanism was revealed through molecular dynamics simulations. Upon 1-propanol introduction, strong hydrogen bond interactions tended to be established between uncovered DETACOO– and DETAH+ and triggered the evolution of phase separation. Furthermore, 1-propanol functioned as an absorption activator by increasing the overall mass transfer coefficient (KG) from 2.11 to 3.22 × 10–10 mol/cm2·s·Pa. DETA–1-propanol achieved a regeneration heat of 2.12 GJ/t CO2, which was 46.9% lower than that of 5 M MEA. This study provides a molecular-scale understanding of the phase separation mechanism and a promising DETA–1-propanol biphasic solvent with favorable phase separation behavior, rapid CO2 absorption, high CO2 absorption capacity, and superior energy-saving regeneration.

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  • Wang, Rujie & Yang, Yuying & Wang, Mengfan & Lin, Jinshan & Zhang, Shihan & An, Shanlong & Wang, Lidong, 2021. "Energy efficient diethylenetriamine–1-propanol biphasic solvent for CO2 capture: Experimental and theoretical study," Applied Energy, Elsevier, vol. 290(C).
    • Handle: RePEc:eee:appene:v:290:y:2021:i:c:s0306261921002750
    DOI: 10.1016/j.apenergy.2021.116768
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    1. Alivand, Masood S. & Mazaheri, Omid & Wu, Yue & Stevens, Geoffrey W. & Scholes, Colin A. & Mumford, Kathryn A., 2019. "Development of aqueous-based phase change amino acid solvents for energy-efficient CO2 capture: The role of antisolvent," Applied Energy, Elsevier, vol. 256(C).
    2. Nwaoha, Chikezie & Tontiwachwuthikul, Paitoon, 2019. "Carbon dioxide capture from pulp mill using 2-amino-2-methyl-1-propanol and monoethanolamine blend: Techno-economic assessment of advanced process configuration," Applied Energy, Elsevier, vol. 250(C), pages 1202-1216.
    3. Bihong, Lv & Kexuan, Yang & Xiaobin, Zhou & Zuoming, Zhou & Guohua, Jing, 2020. "2-Amino-2-methyl-1-propanol based non-aqueous absorbent for energy-efficient and non-corrosive carbon dioxide capture," Applied Energy, Elsevier, vol. 264(C).
    4. Wang, Rujie & Jiang, Lei & Li, Qiangwei & Gao, Ge & Zhang, Shihan & Wang, Lidong, 2020. "Energy-saving CO2 capture using sulfolane-regulated biphasic solvent," Energy, Elsevier, vol. 211(C).
    5. Zhang, Weidong & Jin, Xianhang & Tu, Weiwei & Ma, Qian & Mao, Menglin & Cui, Chunhua, 2017. "Development of MEA-based CO2 phase change absorbent," Applied Energy, Elsevier, vol. 195(C), pages 316-323.
    6. Wang, Rujie & Liu, Shanshan & Wang, Lidong & Li, Qiangwei & Zhang, Shihan & Chen, Bo & Jiang, Lei & Zhang, Yifeng, 2019. "Superior energy-saving splitter in monoethanolamine-based biphasic solvents for CO2 capture from coal-fired flue gas," Applied Energy, Elsevier, vol. 242(C), pages 302-310.
    7. Xiao, Min & Liu, Helei & Gao, Hongxia & Olson, Wilfred & Liang, Zhiwu, 2019. "CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine," Applied Energy, Elsevier, vol. 235(C), pages 311-319.
    8. Wang, Rujie & Liu, Shanshan & Li, Qiangwei & Zhang, Shihan & Wang, Lidong & An, Shanlong, 2021. "CO2 capture performance and mechanism of blended amine solvents regulated by N-methylcyclohexyamine," Energy, Elsevier, vol. 215(PB).
    9. Zhuang, Quan & Clements, Bruce, 2018. "CO2 capture by biphasic absorbent–absorption performance and VLE characteristics," Energy, Elsevier, vol. 147(C), pages 169-176.
    10. Wang, Xianfeng & Akhmedov, Novruz G. & Hopkinson, David & Hoffman, James & Duan, Yuhua & Egbebi, Adefemi & Resnik, Kevin & Li, Bingyun, 2016. "Phase change amino acid salt separates into CO2-rich and CO2-lean phases upon interacting with CO2," Applied Energy, Elsevier, vol. 161(C), pages 41-47.
    11. Wang, Lidong & Yu, Songhua & Li, Qiangwei & Zhang, Yifeng & An, Shanlong & Zhang, Shihan, 2018. "Performance of sulfolane/DETA hybrids for CO2 absorption: Phase splitting behavior, kinetics and thermodynamics," Applied Energy, Elsevier, vol. 228(C), pages 568-576.
    12. Shen, Yao & Chen, Han & Wang, Junliang & Zhang, Shihan & Jiang, Chenkai & Ye, Jiexu & Wang, Lidong & Chen, Jianmeng, 2020. "Two-stage interaction performance of CO2 absorption into biphasic solvents: Mechanism analysis, quantum calculation and energy consumption," Applied Energy, Elsevier, vol. 260(C).
    13. Shen, Yao & Jiang, Chenkai & Zhang, Shihan & Chen, Jun & Wang, Lidong & Chen, Jianmeng, 2018. "Biphasic solvent for CO2 capture: Amine property-performance and heat duty relationship," Applied Energy, Elsevier, vol. 230(C), pages 726-733.
    14. Barzagli, Francesco & Giorgi, Claudia & Mani, Fabrizio & Peruzzini, Maurizio, 2018. "Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy," Applied Energy, Elsevier, vol. 220(C), pages 208-219.
    15. Zhang, Shihan & Shen, Yao & Wang, Lidong & Chen, Jianmeng & Lu, Yongqi, 2019. "Phase change solvents for post-combustion CO2 capture: Principle, advances, and challenges," Applied Energy, Elsevier, vol. 239(C), pages 876-897.
    16. Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.
    17. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
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    6. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    7. Zhou, Xiaobin & Liu, Chao & Zhang, Jie & Fan, Yinming & Zhu, Yinian & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Hongxiang & Zhu, Zongqiang, 2023. "Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator," Energy, Elsevier, vol. 270(C).
    8. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).
    9. Chen, Hao & Dong, Sheying & Zhang, Yaojun & He, Panyang, 2022. "A comparative study on energy efficient CO2 capture using amine grafted solid sorbent: Materials characterization, isotherms, kinetics and thermodynamics," Energy, Elsevier, vol. 239(PD).

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