IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v288y2021ics0306261921001513.html
   My bibliography  Save this article

Thermodynamic evaluation and experimental investigation of CaO-assisted Fe-based chemical looping reforming process for syngas production

Author

Listed:
  • Zhao, Yunlei
  • Jin, Bo
  • Luo, Xiao
  • Liang, Zhiwu

Abstract

Many works have focused on the reactivity and valence transition of Fe-based oxygen carriers in chemical looping partial oxidation reforming process. However, the reforming performance and impacts of operating factors are unclear with the co-feeding of CaO being CO2 carrier to realize simultaneous CO2 capture and utilization. In this work, thermodynamic equilibrium calculation, reactivity test and material characterization are carried out to optimize the process characteristics. The impacts of feeding conditions (Fe/Al weight ratio, methane amount, Ca/Fe mole ratio and packing manner) on the reforming reactivity are obtained to reveal the interaction between CaO and Fe2O3. The gas product distribution indicates that the carbon deposition and oxidation degree is closely related to CH4 amount. The spatial configuration between CaCO3 and Fe2O3 reforming is essential to obtain the desirable reforming products. The difference of FeO existence on the theoretical and experimental phase components illustrates that reaction degree is affected by the reduction agent amount. By comparing the methane temperature-programmed reaction of CaCO3, Fe2O3 and their mixture, it is suggested that the existence of CaCO3 is beneficial for accelerating iron-based methane reforming. This study provides a way to improve reaction degree and optimize process characteristic for chemical looping reforming process.

Suggested Citation

  • Zhao, Yunlei & Jin, Bo & Luo, Xiao & Liang, Zhiwu, 2021. "Thermodynamic evaluation and experimental investigation of CaO-assisted Fe-based chemical looping reforming process for syngas production," Applied Energy, Elsevier, vol. 288(C).
    • Handle: RePEc:eee:appene:v:288:y:2021:i:c:s0306261921001513
    DOI: 10.1016/j.apenergy.2021.116614
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921001513
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2021.116614?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sun, Zhao & Chen, Shiyi & Hu, Jun & Chen, Aimin & Rony, Asif Hasan & Russell, Christopher K. & Xiang, Wenguo & Fan, Maohong & Darby Dyar, M. & Dklute, Elizabeth C., 2018. "Ca2Fe2O5: A promising oxygen carrier for CO/CH4 conversion and almost-pure H2 production with inherent CO2 capture over a two-step chemical looping hydrogen generation process," Applied Energy, Elsevier, vol. 211(C), pages 431-442.
    2. Hu, Xiayi (Eric) & Liu, Libin & Luo, Xiao & Xiao, Gongkui & Shiko, Elenica & Zhang, Rui & Fan, Xianfeng & Zhou, Yefeng & Liu, Yang & Zeng, Zhaogang & Li, Chao'en, 2020. "A review of N-functionalized solid adsorbents for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 260(C).
    3. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    4. Zhu, Min & Chen, Shiyi & Soomro, Ahsanullah & Hu, Jun & Sun, Zhao & Ma, Shiwei & Xiang, Wenguo, 2018. "Effects of supports on reduction activity and carbon deposition of iron oxide for methane chemical looping hydrogen generation," Applied Energy, Elsevier, vol. 225(C), pages 912-921.
    5. Valverde, Jose M. & Sanchez-Jimenez, Pedro E. & Perejon, Antonio & Perez-Maqueda, Luis A., 2013. "Constant rate thermal analysis for enhancing the long-term CO2 capture of CaO at Ca-looping conditions," Applied Energy, Elsevier, vol. 108(C), pages 108-120.
    6. Jing, Jie-ying & Zhang, Xue-wei & Li, Qing & Li, Ting-yu & Li, Wen-ying, 2018. "Self-activation of CaO/Ca3Al2O6 sorbents by thermally pretreated in CO2 atmosphere," Applied Energy, Elsevier, vol. 220(C), pages 419-425.
    7. Huang, Jijiang & Liu, Wen & Hu, Wenting & Metcalfe, Ian & Yang, Yanhui & Liu, Bin, 2019. "Phase interactions in Ni-Cu-Al2O3 mixed oxide oxygen carriers for chemical looping applications," Applied Energy, Elsevier, vol. 236(C), pages 635-647.
    8. Hafizi, A. & Rahimpour, M.R. & Hassanajili, S., 2016. "High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent," Applied Energy, Elsevier, vol. 169(C), pages 629-641.
    9. Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    10. Arshadi, M. & Taghvaei, H. & Abdolmaleki, M.K. & Lee, M. & Eskandarloo, H. & Abbaspourrad, A., 2019. "Carbon dioxide absorption in water/nanofluid by a symmetric amine-based nanodendritic adsorbent," Applied Energy, Elsevier, vol. 242(C), pages 1562-1572.
    11. Jeremiáš, M. & Pohořelý, M. & Svoboda, K. & Skoblia, S. & Beňo, Z. & Šyc, M., 2018. "CO2 gasification of biomass: The effect of lime concentration in a fluidised bed," Applied Energy, Elsevier, vol. 217(C), pages 361-368.
    12. Lee, Sunghoon & Yun, Seokwon & Kim, Jin-Kuk, 2019. "Development of novel sub-ambient membrane systems for energy-efficient post-combustion CO2 capture," Applied Energy, Elsevier, vol. 238(C), pages 1060-1073.
    13. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    14. Lee, Dong-Young & Mehran, Muhammad Taqi & Kim, Jonghwan & Kim, Sangcho & Lee, Seung-Bok & Song, Rak-Hyun & Ko, Eun-Yong & Hong, Jong-Eun & Huh, Joo-Youl & Lim, Tak-Hyoung, 2020. "Scaling up syngas production with controllable H2/CO ratio in a highly efficient, compact, and durable solid oxide coelectrolysis cell unit-bundle," Applied Energy, Elsevier, vol. 257(C).
    15. Li, H. & Yan, J. & Yan, J. & Anheden, M., 2009. "Impurity impacts on the purification process in oxy-fuel combustion based CO2 capture and storage system," Applied Energy, Elsevier, vol. 86(2), pages 202-213, February.
    16. Pelletier, Chloé & Rogaume, Yann & Dieckhoff, Léa & Bardeau, Guillaume & Pons, Marie-Noëlle & Dufour, Anthony, 2019. "Effect of combustion technology and biogenic CO2 impact factor on global warming potential of wood-to-heat chains," Applied Energy, Elsevier, vol. 235(C), pages 1381-1388.
    17. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhu, Min & Chen, Shiyi & Soomro, Ahsanullah & Hu, Jun & Sun, Zhao & Ma, Shiwei & Xiang, Wenguo, 2018. "Effects of supports on reduction activity and carbon deposition of iron oxide for methane chemical looping hydrogen generation," Applied Energy, Elsevier, vol. 225(C), pages 912-921.
    2. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    3. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    4. Cho, Won Chul & Lee, Jun Kyu & Nam, Gyeong Duk & Kim, Chang Hee & Cho, Hyun-Seok & Joo, Jong Hoon, 2019. "Degradation analysis of mixed ionic-electronic conductor-supported iron-oxide oxygen carriers for chemical-looping conversion of methane," Applied Energy, Elsevier, vol. 239(C), pages 644-657.
    5. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    6. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    7. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    8. Nadgouda, Sourabh G. & Guo, Mengqing & Tong, Andrew & Fan, L.-S., 2019. "High purity syngas and hydrogen coproduction using copper-iron oxygen carriers in chemical looping reforming process," Applied Energy, Elsevier, vol. 235(C), pages 1415-1426.
    9. Chein, Rei-Yu & Hsu, Wen-Huai, 2019. "Thermodynamic analysis of syngas production via chemical looping dry reforming of methane," Energy, Elsevier, vol. 180(C), pages 535-547.
    10. Živković, Luka A. & Pohar, Andrej & Likozar, Blaž & Nikačević, Nikola M., 2016. "Kinetics and reactor modeling for CaO sorption-enhanced high-temperature water–gas shift (SE–WGS) reaction for hydrogen production," Applied Energy, Elsevier, vol. 178(C), pages 844-855.
    11. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    12. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.
    13. Gil, María V. & Rout, Kumar R. & Chen, De, 2018. "Production of high pressure pure H2 by pressure swing sorption enhanced steam reforming (PS-SESR) of byproducts in biorefinery," Applied Energy, Elsevier, vol. 222(C), pages 595-607.
    14. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2016. "Energy efficient sorption enhanced-chemical looping methane reforming process for high-purity H2 production: Experimental proof-of-concept," Applied Energy, Elsevier, vol. 180(C), pages 457-471.
    15. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    16. Hsiao Mun Lee & Jiahui Xiong & Xinfei Chen & Haitao Wang & Da Song & Jinlong Xie & Yan Lin & Ya Xiong & Zhen Huang & Hongyu Huang, 2023. "Evaluation of the Reactivity of Hematite Oxygen Carriers Modified Using Alkaline (Earth) Metals and Transition Metals for the Chemical Looping Conversion of Lignite," Energies, MDPI, vol. 16(6), pages 1-16, March.
    17. Jiang, Qiongqiong & Zhang, Hao & Deng, Ya'nan & Kang, Qilan & Hong, Hui & Jin, Hongguang, 2018. "Properties and reactivity of LaCuxNi1−xO3 perovskites in chemical-looping combustion for mid-temperature solar-thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1506-1514.
    18. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    19. Wang, Chao & Liao, Mingzheng & Liang, Bo & Jiang, Zhiqiang & Zhong, Weilin & Chen, Ying & Luo, Xianglong & Shu, Riyang & Tian, Zhipeng & Lei, Libin, 2021. "Enhancement effect of catalyst support on indirect hydrogen production from propane partial oxidation towards commercial solid oxide fuel cell (SOFC) applications," Applied Energy, Elsevier, vol. 288(C).
    20. Song, Xueyi & Yuan, Junjie & Yang, Chen & Deng, Gaofeng & Wang, Zhichao & Gao, Jubao, 2023. "Carbon dioxide separation performance evaluation of amine-based versus choline-based deep eutectic solvents," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:288:y:2021:i:c:s0306261921001513. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.