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Interaction of iron–copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal

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  • Siriwardane, Ranjani V.
  • Ksepko, Ewelina
  • Tian, Hanjing
  • Poston, James
  • Simonyi, Thomas
  • Sciazko, Marek

Abstract

The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800°C to 900°C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900°C and might be successfully used up to 900°C for coal CLC reaction in the presence of steam.

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  • Siriwardane, Ranjani V. & Ksepko, Ewelina & Tian, Hanjing & Poston, James & Simonyi, Thomas & Sciazko, Marek, 2013. "Interaction of iron–copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal," Applied Energy, Elsevier, vol. 107(C), pages 111-123.
    • Handle: RePEc:eee:appene:v:107:y:2013:i:c:p:111-123
    DOI: 10.1016/j.apenergy.2013.01.063
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    1. Wang, Jinsheng & Anthony, Edward J., 2008. "Clean combustion of solid fuels," Applied Energy, Elsevier, vol. 85(2-3), pages 73-79, February.
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    1. Chang, F.C. & Liao, P.H. & Tsai, C.K. & Hsiao, M.C. & Paul Wang, H., 2014. "Chemical-looping combustion of syngas with nano CuO–NiO on chabazite," Applied Energy, Elsevier, vol. 113(C), pages 1731-1736.
    2. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    3. Zhang, Shuai & Xiao, Rui & Zheng, Wenguang, 2014. "Comparative study between fluidized-bed and fixed-bed operation modes in pressurized chemical looping combustion of coal," Applied Energy, Elsevier, vol. 130(C), pages 181-189.
    4. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett, 2017. "Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion react," Applied Energy, Elsevier, vol. 203(C), pages 522-534.
    5. Siriwardane, Ranjani & Riley, Jarrett & Atallah, Chris, 2022. "CO2 utilization potential of a novel calcium ferrite based looping process fueled with coal: Experimental evaluation of various coal feedstocks and thermodynamic integrated process analysis," Applied Energy, Elsevier, vol. 323(C).
    6. Fredrik Hildor & Henrik Leion & Tobias Mattisson, 2022. "Steel Converter Slag as an Oxygen Carrier—Interaction with Sulfur Dioxide," Energies, MDPI, vol. 15(16), pages 1-29, August.
    7. Shuai Zhang & Rui Xiao, 2016. "Performance of iron ore oxygen carrier modified by biomass ashes in coal‐fueled chemical looping combustion," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 6(5), pages 695-709, October.
    8. Siriwardane, Ranjani & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions," Applied Energy, Elsevier, vol. 165(C), pages 952-966.
    9. Ksepko, Ewelina & Sciazko, Marek & Babinski, Piotr, 2014. "Studies on the redox reaction kinetics of Fe2O3–CuO/Al2O3 and Fe2O3/TiO2 oxygen carriers," Applied Energy, Elsevier, vol. 115(C), pages 374-383.
    10. Cho, Won Chul & Lee, Do Yeon & Seo, Myung Won & Kim, Sang Done & Kang, KyoungSoo & Bae, Ki Kwang & Kim, Change Hee & Jeong, SeongUk & Park, Chu Sik, 2014. "Continuous operation characteristics of chemical looping hydrogen production system," Applied Energy, Elsevier, vol. 113(C), pages 1667-1674.
    11. Zhang, Yongxing & Doroodchi, Elham & Moghtaderi, Behdad, 2014. "Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2," Applied Energy, Elsevier, vol. 113(C), pages 1916-1923.
    12. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2018. "Experimental and kinetic analysis for particle scale modeling of a CuO-Fe2O3-Al2O3 oxygen carrier during reduction with H2 in chemical looping combustion applications," Applied Energy, Elsevier, vol. 228(C), pages 1515-1530.
    13. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett & Poston, James, 2020. "A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion," Applied Energy, Elsevier, vol. 262(C).
    14. Siriwardane, Ranjani & Tian, Hanjing & Miller, Duane & Richards, George, 2015. "Fluidized bed testing of commercially prepared MgO-promoted hematite and CuO–Fe2O3 mixed metal oxide oxygen carriers for methane and coal chemical looping combustion," Applied Energy, Elsevier, vol. 157(C), pages 348-357.
    15. Nadgouda, Sourabh G. & Guo, Mengqing & Tong, Andrew & Fan, L.-S., 2019. "High purity syngas and hydrogen coproduction using copper-iron oxygen carriers in chemical looping reforming process," Applied Energy, Elsevier, vol. 235(C), pages 1415-1426.
    16. Zhang, Jinzhi & He, Tao & Wang, Zhiqi & Zhu, Min & Zhang, Ke & Li, Bin & Wu, Jinhu, 2017. "The search of proper oxygen carriers for chemical looping partial oxidation of carbon," Applied Energy, Elsevier, vol. 190(C), pages 1119-1125.
    17. Ksepko, Ewelina & Babiński, Piotr & Nalbandian, Lori, 2017. "The redox reaction kinetics of Sinai ore for chemical looping combustion applications," Applied Energy, Elsevier, vol. 190(C), pages 1258-1274.
    18. Yazdanpanah, M.M. & Forret, A. & Gauthier, T. & Delebarre, A., 2014. "Modeling of CH4 combustion with NiO/NiAl2O4 in a 10kWth CLC pilot plant," Applied Energy, Elsevier, vol. 113(C), pages 1933-1944.
    19. Siriwardane, Ranjani & Benincosa, William & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier," Applied Energy, Elsevier, vol. 183(C), pages 1550-1564.
    20. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    21. Siriwardane, Ranjani & Riley, Jarrett & Benincosa, William & Bayham, Samuel & Bobek, Michael & Straub, Douglas & Weber, Justin, 2021. "Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests," Applied Energy, Elsevier, vol. 286(C).

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