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Absorptive Desulfurization of Model Biogas Stream Using Choline Chloride-Based Deep Eutectic Solvents

Author

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  • Edyta Słupek

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80–233 Gdańsk, Poland)

  • Patrycja Makoś

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80–233 Gdańsk, Poland)

Abstract

The paper presents a synthesis of deep eutectic solvents (DESs) based on choline chloride (ChCl) as hydrogen bond acceptor and phenol (Ph), glycol ethylene (EG), and levulinic acid (Lev) as hydrogen bond donors in 1:2 molar ratio. DESs were successfully used as absorption solvents for removal of dimethyl disulfide (DMDS) from model biogas steam. Several parameters affecting the absorption capacity and absorption rate have been optimized including kinds of DES, temperature, the volume of absorbent, model biogas flow rate, and initial concentration of DMDS. Furthermore, reusability and regeneration of DESs by means of adsorption and nitrogen barbotage followed by the mechanism of absorptive desulfurization by means of density functional theory (DFT) as well as FT-IR analysis were investigated. Experimental results indicate that the most promising DES for biogas purification is ChCl:Ph, due to high absorption capacity, relatively long absorption rate, and easy regeneration. The research on the absorption mechanism revealed that van der Waal interaction is the main driving force for DMDS removal from model biogas.

Suggested Citation

  • Edyta Słupek & Patrycja Makoś, 2020. "Absorptive Desulfurization of Model Biogas Stream Using Choline Chloride-Based Deep Eutectic Solvents," Sustainability, MDPI, vol. 12(4), pages 1-16, February.
    • Handle: RePEc:gam:jsusta:v:12:y:2020:i:4:p:1619-:d:323472
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    References listed on IDEAS

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    1. Tippayawong, N. & Thanompongchart, P., 2010. "Biogas quality upgrade by simultaneous removal of CO2 and H2S in a packed column reactor," Energy, Elsevier, vol. 35(12), pages 4531-4535.
    2. Sun, Qie & Li, Hailong & Yan, Jinying & Liu, Longcheng & Yu, Zhixin & Yu, Xinhai, 2015. "Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 521-532.
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    Cited by:

    1. Edyta Słupek & Patrycja Makoś & Jacek Gębicki, 2020. "Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane," Energies, MDPI, vol. 13(13), pages 1-19, July.

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