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Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane

Author

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  • Edyta Słupek

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80-233 Gdansk, Poland)

  • Patrycja Makoś

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80-233 Gdansk, Poland)

  • Jacek Gębicki

    (Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80-233 Gdansk, Poland)

Abstract

This paper presents the theoretical screening of 23 low-cost deep eutectic solvents (DESs) as absorbents for effective removal of the main impurities from biogas streams using a conductor-like screening model for real solvents (COSMO-RS). Based on thermodynamic parameters, i.e., the activity coefficient, excess enthalpy, and Henry’s constant, two DESs composed of choline chloride: urea in a 1:2 molar ratio (ChCl:U 1:2), and choline chloride: oxalic acid in a 1:2 molar ratio (ChCl:OA 1:2) were selected as the most effective absorbents. The σ-profile and σ-potential were used in order to explain the mechanism of the absorptive removal of CO 2 , H 2 S, and siloxanes from a biogas stream. In addition, an economic analysis was prepared to demonstrate the competitiveness of new DESs in the sorbents market. The unit cost of 1 m 3 of pure bio-methane was estimated to be in the range of 0.35–0.37 EUR, which is comparable to currently used technologies.

Suggested Citation

  • Edyta Słupek & Patrycja Makoś & Jacek Gębicki, 2020. "Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane," Energies, MDPI, vol. 13(13), pages 1-19, July.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:13:p:3379-:d:378986
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    References listed on IDEAS

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    2. Thomas Quaid & M. Toufiq Reza, 2021. "Carbon Capture from Biogas by Deep Eutectic Solvents: A COSMO Study to Evaluate the Effect of Impurities on Solubility and Selectivity," Clean Technol., MDPI, vol. 3(2), pages 1-13, June.
    3. Khan, Muhammad Usman & Lee, Jonathan Tian En & Bashir, Muhammad Aamir & Dissanayake, Pavani Dulanja & Ok, Yong Sik & Tong, Yen Wah & Shariati, Mohammad Ali & Wu, Sarah & Ahring, Birgitte Kiaer, 2021. "Current status of biogas upgrading for direct biomethane use: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).

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