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Organosulfonic acid functionalized montmorillonites as solid catalysts for (trans) esterification of free fatty acids and (waste) oils

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  • Silva, Sónia M.
  • Peixoto, Andreia F.
  • Freire, Cristina

Abstract

Organosulfonic acid functionalized montemorillonite-MMT (K10 and cloisite Na+) were prepared by different methodologies: (a) one-pot organosilylation or sulfonation, and (b) two-step organosilylation followed by sulfonation or oxidation. The physicochemical characterization ensured the success of the selected methodologies to promote HSO3-functionalization including high S contents (2.84 mmol S/g) and acidities up to 6.03 mmol H+/g (K10_PhSO3H).

Suggested Citation

  • Silva, Sónia M. & Peixoto, Andreia F. & Freire, Cristina, 2020. "Organosulfonic acid functionalized montmorillonites as solid catalysts for (trans) esterification of free fatty acids and (waste) oils," Renewable Energy, Elsevier, vol. 146(C), pages 2416-2429.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:2416-2429
    DOI: 10.1016/j.renene.2019.08.073
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    1. Su, Lijuan & Shao, Xiaojie & Chai, Lin & Ge, Hui & Wang, Hongliang & Cui, Xiaojing & Deng, Tiansheng & Hou, Xianglin, 2022. "Efficiently and directly produce triacetylglycerol from oils and fats over mesoporous polymeric solid acid catalysts," Renewable Energy, Elsevier, vol. 197(C), pages 432-442.

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    More about this item

    Keywords

    Montmorillonite; K10; Cloisite; Organosilane; Esterification; Biodiesel; Organosulfonic acid solid catalysts;
    All these keywords.

    JEL classification:

    • K10 - Law and Economics - - Basic Areas of Law - - - General (Constitutional Law)

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