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Catalytic upgrading of bio-oils over high alumina zeolites

Author

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  • Chaihad, Nichaboon
  • Karnjanakom, Surachai
  • Kurnia, Irwan
  • Yoshida, Akihiro
  • Abudula, Abuliti
  • Reubroycharoen, Prasert
  • Guan, Guoqing

Abstract

Catalytic upgrading of bio-oils derived from fast pyrolysis of sunflower stalk, cedar, knotweed and apple tree stem over H-ZSM-5, H-beta and H-USY zeolites with high alumina content was investigated at a reaction temperature of 500 °C. All catalysts showed high catalytic activity and selectivity towards aromatic hydrocarbons in the conversions of oxygenated compounds in the bio-oils, and 56.2–100% of aromatic hydrocarbons were found in the upgraded bio-oils which can be detected by GC/MS. Naphthalene was favored to be produced by using H-ZSM-5 while more monocyclic aromatic hydrocarbons such as p-xylene, toluene and alkylbenzene were generated by using H-beta as well as H-USY. Furthermore, all catalysts maintained high activity and selectivity with the maximum aromatic hydrocarbons amount of 70% in the upgraded bio-oils detected in the third cycle. In addition, the spent catalysts were easily regenerated by simple calcination at 650 °C for 30 min, and the regenerated catalysts showed almost the same activity as the fresh ones. It is expected that these high alumina zeolites can be widely used in practical bio-oil upgrading processes.

Suggested Citation

  • Chaihad, Nichaboon & Karnjanakom, Surachai & Kurnia, Irwan & Yoshida, Akihiro & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2019. "Catalytic upgrading of bio-oils over high alumina zeolites," Renewable Energy, Elsevier, vol. 136(C), pages 1304-1310.
  • Handle: RePEc:eee:renene:v:136:y:2019:i:c:p:1304-1310
    DOI: 10.1016/j.renene.2018.09.102
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    1. Vichaphund, Supawan & Aht-ong, Duangdao & Sricharoenchaikul, Viboon & Atong, Duangduen, 2015. "Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods," Renewable Energy, Elsevier, vol. 79(C), pages 28-37.
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    1. Chaihad, Nichaboon & Situmorang, Yohanes Andre & Anniwaer, Aisikaer & Kurnia, Irwan & Karnjanakom, Surachai & Kasai, Yutaka & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2021. "Preparation of various hierarchical HZSM-5 based catalysts for in-situ fast upgrading of bio-oil," Renewable Energy, Elsevier, vol. 169(C), pages 283-292.
    2. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    3. Shu, Riyang & Jiang, Hao & Xie, Long & Liu, Xiaozhou & Yin, Tao & Tian, Zhipeng & Wang, Chao & Chen, Ying, 2023. "Efficient hydrodeoxygenation of lignin-derived phenolic compounds by using Ru-based biochar catalyst coupled with silicotungstic acid," Renewable Energy, Elsevier, vol. 202(C), pages 1160-1168.
    4. Huang, Yongcheng & Li, Yaoting & Han, Xudong & Zhang, Jiating & Luo, Kun & Yang, Shangsheng & Wang, Jiyuan, 2020. "Investigation on fuel properties and engine performance of the extraction phase liquid of bio-oil/biodiesel blends," Renewable Energy, Elsevier, vol. 147(P1), pages 1990-2002.

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