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Combined NMR structural characterization and thermogravimetric analyses for the assessment of the AAEM effect during lignocellulosic biomass pyrolysis

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  • Haddad, Khouloud
  • Jeguirim, Mejdi
  • Jellali, Salah
  • Guizani, Chamseddine
  • Delmotte, Luc
  • Bennici, Simona
  • Limousy, Lionel

Abstract

The goal of the present research is to study the effect of the inorganic species on the pyrolysis mechanism of lignocellulosic biomass. Many contradictions as the catalytic role of inorganic salts characterize the research works published up to now. These ambiguities are reasonably due to the morphological and structural modifications of the reacting biomass by the various demineralization and impregnation methods, that impact on the pyrolysis mechanism. In order to clarify the effect of inorganics on the pyrolysis mechanism, alkali and alkaline earth (AAEM) containing salts were deposited by impregnation method on cypress sawdust. Nuclear magnetic resonance analyses showed that the biomass structure was preserved and that metal deposition passes through a cationic exchange mechanism.

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  • Haddad, Khouloud & Jeguirim, Mejdi & Jellali, Salah & Guizani, Chamseddine & Delmotte, Luc & Bennici, Simona & Limousy, Lionel, 2017. "Combined NMR structural characterization and thermogravimetric analyses for the assessment of the AAEM effect during lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 134(C), pages 10-23.
  • Handle: RePEc:eee:energy:v:134:y:2017:i:c:p:10-23
    DOI: 10.1016/j.energy.2017.06.022
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    1. Wang, Kaige & Zhang, Jing & Shanks, Brent H. & Brown, Robert C., 2015. "The deleterious effect of inorganic salts on hydrocarbon yields from catalytic pyrolysis of lignocellulosic biomass and its mitigation," Applied Energy, Elsevier, vol. 148(C), pages 115-120.
    2. Kraiem, Nesrine & Jeguirim, Mejdi & Limousy, Lionel & Lajili, Marzouk & Dorge, Sophie & Michelin, Laure & Said, Rachid, 2014. "Impregnation of olive mill wastewater on dry biomasses: Impact on chemical properties and combustion performances," Energy, Elsevier, vol. 78(C), pages 479-489.
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    4. Bouraoui, Zeineb & Jeguirim, Mejdi & Guizani, Chamseddine & Limousy, Lionel & Dupont, Capucine & Gadiou, Roger, 2015. "Thermogravimetric study on the influence of structural, textural and chemical properties of biomass chars on CO2 gasification reactivity," Energy, Elsevier, vol. 88(C), pages 703-710.
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