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Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas

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  • Li, Zheng
  • Zhong, Dong-Liang
  • Lu, Yi-Yu
  • Yan, Jin
  • Zou, Zhen-Lin

Abstract

This work presents an investigation of using tetra-n-butyl phosphonium bromide (TBPB) semiclathrate hydrate for CO2 capture from simulated shale gas that is composed of 40% CO2 and 60% CH4 in mole fraction. The experiments were performed in a stirred tank reactor with the mass fraction of TBPB (wTBPB) varying from 5.0% to 33.2%. The phase equilibrium data of TBPB semiclathrate hydrate formed in the presence of the 40% CO2/CH4 gas mixture were measured and reported. The effects of TBPB concentration on gas solubility, hydrate formation kinetics, and CO2 separation efficiency were investigated in the temperature range of 278.1–284.2K with the initial pressure fixed at 2.8MPa. The results indicated that at a fixed driving force (overpressure), the gas uptake obtained at the induction time was nearly constant, despite the variation in TBPB concentration, while the rate of hydrate formation increased with the increase in TBPB concentration. Compared to the results obtained at a mole fraction of 1% THF, it was found that enhanced hydrate formation kinetics, a higher CO2 separation factor (31.7±3.3), and a higher operating temperature (284.2K) were obtained at the stoichiometric TBPB concentration (wTBPB=33.2%). Therefore, TBPB may be used as a promising promoter for hydrate-based CO2 capture from the simulated shale gas (CO2/CH4 gas mixture).

Suggested Citation

  • Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    • Handle: RePEc:eee:appene:v:199:y:2017:i:c:p:370-381
    DOI: 10.1016/j.apenergy.2017.05.043
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    as
    1. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    2. Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    3. Zhong, Dong-Liang & Li, Zheng & Lu, Yi-Yu & Wang, Jia-Le & Yan, Jin, 2015. "Evaluation of CO2 removal from a CO2+CH4 gas mixture using gas hydrate formation in liquid water and THF solutions," Applied Energy, Elsevier, vol. 158(C), pages 133-141.
    4. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    5. Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2014. "Hydrogen storage in clathrate hydrates: Current state of the art and future directions," Applied Energy, Elsevier, vol. 122(C), pages 112-132.
    6. Wang, Fei & Fu, Shanfei & Guo, Gang & Jia, Zhen-Zhen & Luo, Sheng-Jun & Guo, Rong-Bo, 2016. "Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture," Energy, Elsevier, vol. 104(C), pages 76-84.
    7. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    8. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    9. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    10. Wang, Qiang & Chen, Xi & Jha, Awadhesh N. & Rogers, Howard, 2014. "Natural gas from shale formation – The evolution, evidences and challenges of shale gas revolution in United States," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 1-28.
    11. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    12. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    13. Tomita, Shuhei & Akatsu, Satoru & Ohmura, Ryo, 2015. "Experiments and thermodynamic simulations for continuous separation of CO2 from CH4+CO2 gas mixture utilizing hydrate formation," Applied Energy, Elsevier, vol. 146(C), pages 104-110.
    14. Yang, Mingjun & Song, Yongchen & Jiang, Lanlan & Zhao, Yuechao & Ruan, Xuke & Zhang, Yi & Wang, Shanrong, 2014. "Hydrate-based technology for CO2 capture from fossil fuel power plants," Applied Energy, Elsevier, vol. 116(C), pages 26-40.
    15. Zhong, Dong-Liang & Wang, Jia-Le & Lu, Yi-Yu & Li, Zheng & Yan, Jin, 2016. "Precombustion CO2 capture using a hybrid process of adsorption and gas hydrate formation," Energy, Elsevier, vol. 102(C), pages 621-629.
    16. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    17. Yuan, Jiehui & Luo, Dongkun & Feng, Lianyong, 2015. "A review of the technical and economic evaluation techniques for shale gas development," Applied Energy, Elsevier, vol. 148(C), pages 49-65.
    18. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.
    19. Guo, Meiyu & Lu, Xi & Nielsen, Chris P. & McElroy, Michael B. & Shi, Wenrui & Chen, Yuntian & Xu, Yuan, 2016. "Prospects for shale gas production in China: Implications for water demand," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 742-750.
    20. Middleton, Richard S. & Carey, J. William & Currier, Robert P. & Hyman, Jeffrey D. & Kang, Qinjun & Karra, Satish & Jiménez-Martínez, Joaquín & Porter, Mark L. & Viswanathan, Hari S., 2015. "Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO2," Applied Energy, Elsevier, vol. 147(C), pages 500-509.
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    7. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    8. Wang, Yan & Zhong, Dong-Liang & Li, Zheng & Li, Jian-Bo, 2020. "Application of tetra-n-butyl ammonium bromide semi-clathrate hydrate for CO2 capture from unconventional natural gases," Energy, Elsevier, vol. 197(C).
    9. Muromachi, Sanehiro & Ikeda, Kosuke & Maesaka, Kazuki & Miyamoto, Hiroyuki, 2024. "Biogas separation by semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts," Energy, Elsevier, vol. 290(C).
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