IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v290y2024ics0360544223035703.html
   My bibliography  Save this article

Biogas separation by semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts

Author

Listed:
  • Muromachi, Sanehiro
  • Ikeda, Kosuke
  • Maesaka, Kazuki
  • Miyamoto, Hiroyuki

Abstract

CH4/CO2 gas separation which frequently appears in biomass energy remains as a kind of challenge for gas hydrates, since these two molecules are similarly preferred by the hydrate phases. Semiclathrate hydrates can improve gas capture preference from the canonical gas hydrates by unique phase behavior. In this study, we perform parametric gas separation tests by the semiclathrate hydrates formed from major four ionic guests, i.e., TBAB, TBAC, TBPB and TBPC with pressure conditions of 1, 3 and 5 MPa and aqueous salt concentrations of 0.10, 0.20, 0.30 in mass fraction. The captured CO2 amounts basically increased with aqueous concentrations. The highest CO2 capture amount was obtained by the TBAB solution with 0.30 in salt mass fraction. TBAC showed the highest CO2 selectivity, while interestingly, the lower the pressure, the higher the CO2 composition in the TBAC hydrate phase, which means that the low-cost operation without high compression of biogas could be feasible and reasonable with this material. TBAB showed relatively simple behavior compared to N2 + CO2 and H2 + CO2 systems. The present results showed that it is possible to eliminate CH4 and enrich CO2 in the hydrate phase when the ionic guest and thermodynamic conditions are appropriately chosen.

Suggested Citation

  • Muromachi, Sanehiro & Ikeda, Kosuke & Maesaka, Kazuki & Miyamoto, Hiroyuki, 2024. "Biogas separation by semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts," Energy, Elsevier, vol. 290(C).
    • Handle: RePEc:eee:energy:v:290:y:2024:i:c:s0360544223035703
    DOI: 10.1016/j.energy.2023.130176
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223035703
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.130176?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    3. Horii, Shunsuke & Ohmura, Ryo, 2018. "Continuous separation of CO2 from a H2 + CO2 gas mixture using clathrate hydrate," Applied Energy, Elsevier, vol. 225(C), pages 78-84.
    4. Chen, Zhaoyang & Fang, Jie & Xu, Chungang & Xia, Zhiming & Yan, Kefeng & Li, Xiaosen, 2020. "Carbon dioxide hydrate separation from Integrated Gasification Combined Cycle (IGCC) syngas by a novel hydrate heat-mass coupling method," Energy, Elsevier, vol. 199(C).
    5. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    6. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    7. Muromachi, Sanehiro, 2021. "CO2 capture properties of semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts from H2 + CO2 mixed gas," Energy, Elsevier, vol. 223(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Muromachi, Sanehiro, 2021. "CO2 capture properties of semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts from H2 + CO2 mixed gas," Energy, Elsevier, vol. 223(C).
    2. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    3. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    4. Chen, Zhaoyang & Fang, Jie & Xu, Chungang & Xia, Zhiming & Yan, Kefeng & Li, Xiaosen, 2020. "Carbon dioxide hydrate separation from Integrated Gasification Combined Cycle (IGCC) syngas by a novel hydrate heat-mass coupling method," Energy, Elsevier, vol. 199(C).
    5. Wang, Yan & Zhong, Dong-Liang & Englezos, Peter & Yan, Jin & Ge, Bin-Bin, 2020. "Kinetic study of semiclathrate hydrates formed with CO2 in the presence of tetra-n-butyl ammonium bromide and tetra-n-butyl phosphonium bromide," Energy, Elsevier, vol. 212(C).
    6. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    7. Wang, Yan & Zhong, Dong-Liang & Li, Zheng & Li, Jian-Bo, 2020. "Application of tetra-n-butyl ammonium bromide semi-clathrate hydrate for CO2 capture from unconventional natural gases," Energy, Elsevier, vol. 197(C).
    8. Cai, Jing & Zhang, Yu & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2018. "Raman spectroscopic studies on carbon dioxide separation from fuel gas via clathrate hydrate in the presence of tetrahydrofuran," Applied Energy, Elsevier, vol. 214(C), pages 92-102.
    9. Zang, Xiaoya & Wang, Jing & He, Yong & Zhou, Xuebing & Liang, Deqing, 2022. "Formation kinetics and microscopic characteristics of synthesized ternary gas mixture hydrates in TBAB aqueous solutions," Energy, Elsevier, vol. 245(C).
    10. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    11. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    12. Dong, Hongsheng & Wang, Jiaqi & Xie, Zhuoxue & Wang, Bin & Zhang, Lunxiang & Shi, Quan, 2021. "Potential applications based on the formation and dissociation of gas hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    13. Xueping Chen & Shuaijun Li & Peng Zhang & Wenting Chen & Qingbai Wu & Jing Zhan & Yingmei Wang, 2021. "Promoted Disappearance of CO 2 Hydrate Self-Preservation Effect by Surfactant SDS," Energies, MDPI, vol. 14(13), pages 1-14, June.
    14. Najmus S. Sifat & Yousef Haseli, 2019. "A Critical Review of CO 2 Capture Technologies and Prospects for Clean Power Generation," Energies, MDPI, vol. 12(21), pages 1-33, October.
    15. Omran, Ahmed & Nesterenko, Nikolay & Valtchev, Valentin, 2022. "Zeolitic ice: A route toward net zero emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    16. Ma, Fei & Zhang, Peng, 2019. "A review of thermo-fluidic performance and application of shellless phase change slurry: Part 1 – Preparations, properties and applications," Energy, Elsevier, vol. 189(C).
    17. Chen, Siyuan & Wang, Yanhong & Lang, Xuemei & Fan, Shuanshi & Li, Gang, 2023. "Rapid and high hydrogen storage in epoxycyclopentane hydrate at moderate pressure," Energy, Elsevier, vol. 268(C).
    18. Cheng, Zucheng & Sun, Lintao & Liu, Yingying & Jiang, Lanlan & Chen, Bingbing & Song, Yongchen, 2023. "Study on the micro-macro kinetic and amino acid-enhanced separation of CO2-CH4 via sII hydrate," Renewable Energy, Elsevier, vol. 218(C).
    19. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    20. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:290:y:2024:i:c:s0360544223035703. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.