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Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries

Author

Listed:
  • Wei, L.
  • Zhao, T.S.
  • Zeng, L.
  • Zhou, X.L.
  • Zeng, Y.K.

Abstract

A copper nanoparticle deposited graphite felt electrode for all vanadium redox flow batteries (VRFBs) is developed and tested. It is found that the copper catalyst enables a significant improvement in the electrochemical kinetics of the V3+/V2+ redox reaction. The battery’s utilization of the electrolyte and energy efficiency are found to be as high as 83.7% and 80.1%, at a current density of 300mAcm−2, which are 53.1% and 17.8% higher than those of the battery without the catalyst. Moreover, the present battery shows a good stability during the cycle test. The results suggest that the inexpensive copper nanoparticle catalyst without tedious preparation process offers a great promise for VRFB application.

Suggested Citation

  • Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    • Handle: RePEc:eee:appene:v:180:y:2016:i:c:p:386-391
    DOI: 10.1016/j.apenergy.2016.07.134
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    References listed on IDEAS

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    1. Bin Li & Zimin Nie & M. Vijayakumar & Guosheng Li & Jun Liu & Vincent Sprenkle & Wei Wang, 2015. "Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery," Nature Communications, Nature, vol. 6(1), pages 1-8, May.
    2. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    3. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    4. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
    5. Mohamed, M.R. & Leung, P.K. & Sulaiman, M.H., 2015. "Performance characterization of a vanadium redox flow battery at different operating parameters under a standardized test-bed system," Applied Energy, Elsevier, vol. 137(C), pages 402-412.
    6. Wei, Zhongbao & Lim, Tuti Mariana & Skyllas-Kazacos, Maria & Wai, Nyunt & Tseng, King Jet, 2016. "Online state of charge and model parameter co-estimation based on a novel multi-timescale estimator for vanadium redox flow battery," Applied Energy, Elsevier, vol. 172(C), pages 169-179.
    7. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    8. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    9. Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.
    10. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
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    Cited by:

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    2. Wang, Tao & Fu, Jiahui & Zheng, Menglian & Yu, Zitao, 2018. "Dynamic control strategy for the electrolyte flow rate of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 227(C), pages 613-623.
    3. Sun, J. & Jiang, H.R. & Wu, M.C. & Fan, X.Z. & Chao, C.Y.H. & Zhao, T.S., 2020. "Aligned hierarchical electrodes for high-performance aqueous redox flow battery," Applied Energy, Elsevier, vol. 271(C).
    4. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    5. Mehboob, Sheeraz & Ali, Ghulam & Shin, Hyun-Jin & Hwang, Jinyeon & Abbas, Saleem & Chung, Kyung Yoon & Ha, Heung Yong, 2018. "Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles," Applied Energy, Elsevier, vol. 229(C), pages 910-921.
    6. Ren, Y.X. & Zhao, T.S. & Tan, P. & Wei, Z.H. & Zhou, X.L., 2017. "Modeling of an aprotic Li-O2 battery incorporating multiple-step reactions," Applied Energy, Elsevier, vol. 187(C), pages 706-716.
    7. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    8. Igor Iwakiri & Tiago Antunes & Helena Almeida & João P. Sousa & Rita Bacelar Figueira & Adélio Mendes, 2021. "Redox Flow Batteries: Materials, Design and Prospects," Energies, MDPI, vol. 14(18), pages 1-45, September.
    9. Simon, Benedict A. & Gayon-Lombardo, Andrea & Pino-Muñoz, Catalina A. & Wood, Charles E. & Tenny, Kevin M. & Greco, Katharine V. & Cooper, Samuel J. & Forner-Cuenca, Antoni & Brushett, Fikile R. & Kuc, 2022. "Combining electrochemical and imaging analyses to understand the effect of electrode microstructure and electrolyte properties on redox flow batteries," Applied Energy, Elsevier, vol. 306(PB).

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