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A double-layer electrode for the negative side of deep eutectic solvent electrolyte-based vanadium-iron redox flow battery

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  • Ma, Qiang
  • Fu, Wenxuan
  • Zhao, Lijuan
  • Chen, Zhenqian
  • Su, Huaneng
  • Xu, Qian

Abstract

This work designs a double-layer porous electrode spliced by carbon paper and graphite felt. A low-porosity carbon paper electrode treated by thermal oxidation is assembled near the membrane, which is used to promote the kinetics of vanadium redox reaction, and the increased hydrophilicity of electrode also facilitates the convective mass transfer process. On the other hand, a high-porosity graphite felt electrode deposited with copper nanoparticles is assembled near the flow field, which has the high permeability, conductivity and interface catalytic efficiency to reduce flow/ions/charge transfer resistances. Cyclic voltammetry illustrates that the copper nanoparticles deposited on the surface of carbon electrode can play the role to enhance the electrochemical activity of the negative electrode with lower potential. Consequently, the double-layer porous electrode is assembled as a negative side of deep eutectic solvent electrolyte-based vanadium-iron redox flow battery (RFB). The experimental study shows this modified RFB has an energy efficiency of 91.8% at the relatively low current density (2 mA cm−2), and a peak power density of 12.71 mW cm−2, which are 12.2% and 30.2% higher than that of pristine graphite electrode, respectively. The results demonstrate the superiority of this design strategy of double-layer electrode for potential applications.

Suggested Citation

  • Ma, Qiang & Fu, Wenxuan & Zhao, Lijuan & Chen, Zhenqian & Su, Huaneng & Xu, Qian, 2023. "A double-layer electrode for the negative side of deep eutectic solvent electrolyte-based vanadium-iron redox flow battery," Energy, Elsevier, vol. 265(C).
    • Handle: RePEc:eee:energy:v:265:y:2023:i:c:s0360544222031772
    DOI: 10.1016/j.energy.2022.126291
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    References listed on IDEAS

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    1. Chen, Wei & Kang, Jialun & Shu, Qing & Zhang, Yunsong, 2019. "Analysis of storage capacity and energy conversion on the performance of gradient and double-layered porous electrode in all-vanadium redox flow batteries," Energy, Elsevier, vol. 180(C), pages 341-355.
    2. Wang, Rui & Li, Yinshi & Wang, Yanning & Fang, Zhou, 2020. "Phosphorus-doped graphite felt allowing stabilized electrochemical interface and hierarchical pore structure for redox flow battery," Applied Energy, Elsevier, vol. 261(C).
    3. Yang, Zaoli & Ghadamyari, Mojtaba & Khorramdel, Hossein & Seyed Alizadeh, Seyed Mehdi & Pirouzi, Sasan & Milani, Muhammed & Banihashemi, Farzad & Ghadimi, Noradin, 2021. "Robust multi-objective optimal design of islanded hybrid system with renewable and diesel sources/stationary and mobile energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    5. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
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    Cited by:

    1. Al-Farsi, Raiyan & Hayyan, Maan, 2023. "Paving the way for advancement of renewable energy technologies using deep eutectic solvents: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    2. Yesilyurt, Muhammed Samil & Ozcan, Huseyin Gunhan & Yavasoglu, Huseyin Ayhan, 2023. "Co-simulation-based conventional exergy evaluation of a hybrid energy generation-vanadium redox flow battery-air source heat pump system," Energy, Elsevier, vol. 281(C).

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