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Cyclohexanedione as the negative electrode reaction for aqueous organic redox flow batteries

Author

Listed:
  • Leung, P.
  • Martin, T.
  • Liras, M.
  • Berenguer, A.M.
  • Marcilla, R.
  • Shah, A.
  • An, L.
  • Anderson, M.A.
  • Palma, J.

Abstract

The electrochemical reduction and oxidation of cyclohexanedione is evaluated for the first time as the negative electrode reaction in an organic redox flow battery. Electrochemical characterization indicates that the redox reaction of cyclohexanedione is a proton-coupled electron transfer process with quasi-reversible behavior in acidic media (pH<3). Among three isomeric compounds (1,2-, 1,3- and 1,4-cyclohexanedione), the reduction of 1,3-cyclohexanedione exhibits the most negative electrode potential (c.a. −0.6Vvs. Ag|AgCl (c.a. −0.4Vvs. NHE)) as well as the widest pH operating range (pH 1–5) for relatively reversible reactions. The resulting electrode potential is the most negative of those to have been reported in neutral/acidic electrolytes. 1,3-cyclohexanedione is subsequently used as the active species in the negative electrode of a parallel plate flow cell, which is charge-discharge cycled at 3.4mAcm−2 for 100 cycles, yielding half-cell coulombic efficiencies of c.a. 99%. The organic molecules derived from this group are observed to have high solubilities (>2M) and exhibit reduction process with up to 4 electrons transferred.

Suggested Citation

  • Leung, P. & Martin, T. & Liras, M. & Berenguer, A.M. & Marcilla, R. & Shah, A. & An, L. & Anderson, M.A. & Palma, J., 2017. "Cyclohexanedione as the negative electrode reaction for aqueous organic redox flow batteries," Applied Energy, Elsevier, vol. 197(C), pages 318-326.
    • Handle: RePEc:eee:appene:v:197:y:2017:i:c:p:318-326
    DOI: 10.1016/j.apenergy.2017.04.023
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    References listed on IDEAS

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    Cited by:

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    3. Wei, L. & Wu, M.C. & Zhao, T.S. & Zeng, Y.K. & Ren, Y.X., 2018. "An aqueous alkaline battery consisting of inexpensive all-iron redox chemistries for large-scale energy storage," Applied Energy, Elsevier, vol. 215(C), pages 98-105.
    4. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    5. Jiang, H.R. & Shyy, W. & Ren, Y.X. & Zhang, R.H. & Zhao, T.S., 2019. "A room-temperature activated graphite felt as the cost-effective, highly active and stable electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 544-553.
    6. Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.
    7. Jiang, H.R. & Zeng, Y.K. & Wu, M.C. & Shyy, W. & Zhao, T.S., 2019. "A uniformly distributed bismuth nanoparticle-modified carbon cloth electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 240(C), pages 226-235.

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