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A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery

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  • Chou, Yi-Sin
  • Hsu, Ning-Yih
  • Jeng, King-Tsai
  • Chen, Kuan-Hsiang
  • Yen, Shi-Chern

Abstract

A novel ultrasonic velocity sensing approach is proposed and investigated to monitor the state of charge (SOC) of a vanadium redox flow battery (VRB, or VRFB). The positive electrode is designated as the energy storage capacity-limiting one so that the molar ratio of the V5+ ion in the positive electrolyte solution determines the SOC of a VRB. The tested single-cell VRB is connected to an ultrasonic sensor and charged/discharged almost to its two extremes at a constant current of 2A under various operating temperatures. It is found that the ultrasound velocity exhibits distinct variations in accordance with changes of vanadium ion compositions in the positive electrolyte solution as the SOC of the VRB varies. The SOC obtained can be depicted in a 3D plot in terms of ultrasound velocity and operating temperature. An empirical model equation is proposed and found to fit the experimental results of both charging and discharging stages quite well. The advantages of this SOC sensing approach are that it is totally independent of VRB operations and can be readily applied to both sides of the electrodes. It is expected to develop into a dependable method for accurate and real-time monitoring of SOC for VRB.

Suggested Citation

  • Chou, Yi-Sin & Hsu, Ning-Yih & Jeng, King-Tsai & Chen, Kuan-Hsiang & Yen, Shi-Chern, 2016. "A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery," Applied Energy, Elsevier, vol. 182(C), pages 253-259.
    • Handle: RePEc:eee:appene:v:182:y:2016:i:c:p:253-259
    DOI: 10.1016/j.apenergy.2016.08.125
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    References listed on IDEAS

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    1. Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.
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    Cited by:

    1. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    2. Chao-Tsung Ma, 2020. "A Novel State of Charge Estimating Scheme Based on an Air-Gap Fiber Interferometer Sensor for the Vanadium Redox Flow Battery," Energies, MDPI, vol. 13(2), pages 1-13, January.
    3. Li, Xiangrong & Xiong, Jing & Tang, Ao & Qin, Ye & Liu, Jianguo & Yan, Chuanwei, 2018. "Investigation of the use of electrolyte viscosity for online state-of-charge monitoring design in vanadium redox flow battery," Applied Energy, Elsevier, vol. 211(C), pages 1050-1059.

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