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Numerical investigations on ethanol electrolysis for production of pure hydrogen from renewable sources

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  • Ehteshami, S. Mohsen Mousavi
  • Vignesh, S.
  • Rasheed, R.K.A.
  • Chan, S.H.

Abstract

Hydrogen and fuel cells have the potential to play a significant role in the energy-mix network and providing a more sustainable future. Hydrogen is mainly produced from steam-reforming of natural gas and water electrolysis. However, it is suspected that the production of hydrogen through the electrolysis of ethanol is more energy efficient and more environmentally friendly. In this study, to gain a good insight of ethanol electrolysis process, we have investigated the ethanol electrolysis in a polymer electrolyte membrane (PEM) reactor numerically. A two-dimensional, isothermal, and single phase ethanol electrolyzer numerical model, taking into account the transport phenomena and electrochemical reactions, has been developed for such purpose. Besides, a systematic parametric study is carried out to elucidate the effect of operating temperature, flow rate and the thickness of the membrane on the performance of the electrolytic cell. A reasonable agreement is found between the numerical data and the experimental results available in the literature indicating the predictive capability of the model.

Suggested Citation

  • Ehteshami, S. Mohsen Mousavi & Vignesh, S. & Rasheed, R.K.A. & Chan, S.H., 2016. "Numerical investigations on ethanol electrolysis for production of pure hydrogen from renewable sources," Applied Energy, Elsevier, vol. 170(C), pages 388-393.
    • Handle: RePEc:eee:appene:v:170:y:2016:i:c:p:388-393
    DOI: 10.1016/j.apenergy.2016.03.001
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    2. Qolipour, Mojtaba & Mostafaeipour, Ali & Tousi, Omid Mohseni, 2017. "Techno-economic feasibility of a photovoltaic-wind power plant construction for electric and hydrogen production: A case study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 113-123.
    3. Kang, Zhenye & Mo, Jingke & Yang, Gaoqiang & Li, Yifan & Talley, Derrick A. & Retterer, Scott T. & Cullen, David A. & Toops, Todd J. & Brady, Michael P. & Bender, Guido & Pivovar, Bryan S. & Green, Jo, 2017. "Thin film surface modifications of thin/tunable liquid/gas diffusion layers for high-efficiency proton exchange membrane electrolyzer cells," Applied Energy, Elsevier, vol. 206(C), pages 983-990.
    4. Ju, HyungKuk & Badwal, Sukhvinder & Giddey, Sarbjit, 2018. "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production," Applied Energy, Elsevier, vol. 231(C), pages 502-533.
    5. Zhang, Baoxu & Chen, Yumin & Zhang, Bing & Peng, Ruifeng & Lu, Qiancheng & Yan, Weijie & Yu, Bo & Liu, Fang & Zhang, Junying, 2022. "Cyclic performance of coke oven gas - Steam reforming with assistance of steel slag derivates for high purity hydrogen production," Renewable Energy, Elsevier, vol. 184(C), pages 592-603.

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