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Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels

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  • Arjmand, Mehdi
  • Leion, Henrik
  • Mattisson, Tobias
  • Lyngfelt, Anders

Abstract

The chemical-looping combustion (CLC) process is a novel solution for efficient combustion with direct capture of carbon dioxide. The process uses a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. In this work, six different manganese ores are investigated as oxygen carriers for CLC application. The chemical-looping characteristics of the oxygen carriers were evaluated in a laboratory-scale fluidized-bed reactor in the temperature range of 900–970°C during alternating reducing and oxidizing conditions. Three of the manganese ores showed a small oxygen release in inert environment between 850 and 950°C. During reactivity tests, the gas yield with methane increased with the temperature and complete conversion of 50% CO in H2 was obtained for all of the ores. The rates of char gasification of two fuels, namely Mexican petroleum coke and Swedish wood char, were compared for the different manganese ores at 970°C and with 50% H2O in N2 as fluidizing gas. Ilmenite and a manufactured Mn-oxide oxygen carrier consisting of Mn3O4 and MgO-stabilized ZrO2 as support were also included for comparison. The char gasification rate and the gas conversion were higher with the manganese ores and the Mn-oxide oxygen carrier compared to ilmenite. However, the higher reactivity of the manganese ores with H2 and the ensuing decrease in H2 inhibition for manganese ores is not sufficient to explain their higher rate of char gasification. Surface analysis of partially gasified petcoke particles in the presence of manganese ores showed formation of cavities and channels as well as a uniform distribution of potassium and sodium elements. The rate of char gasification also increased with the concentration of potassium and sodium impurities in the manganese ores. Thus the results suggest that the increased rate of char conversion for manganese ores is due to alkali-catalyzed steam gasification. The increase in rate of char gasification, in combination with potentially low costs of these materials suggests that manganese ores could be interesting materials for CLC with solid fuels.

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  • Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:1883-1894
    DOI: 10.1016/j.apenergy.2013.06.015
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    1. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
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    1. Chang, F.C. & Liao, P.H. & Tsai, C.K. & Hsiao, M.C. & Paul Wang, H., 2014. "Chemical-looping combustion of syngas with nano CuO–NiO on chabazite," Applied Energy, Elsevier, vol. 113(C), pages 1731-1736.
    2. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    3. Källén, Malin & Rydén, Magnus & Lyngfelt, Anders & Mattisson, Tobias, 2015. "Chemical-looping combustion using combined iron/manganese/silicon oxygen carriers," Applied Energy, Elsevier, vol. 157(C), pages 330-337.
    4. Cheng, Xianming & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Zhouhang & Long, Yanhui & Zheng, Min & Tian, Dong & Wang, Hua, 2018. "Enhanced performance of chemical looping combustion of methane by combining oxygen carriers via optimizing the stacking sequences," Applied Energy, Elsevier, vol. 230(C), pages 696-711.
    5. Wang, Kun & Tian, Xin & Zhao, Haibo, 2016. "Sulfur behavior in chemical-looping combustion using a copper ore oxygen carrier," Applied Energy, Elsevier, vol. 166(C), pages 84-95.
    6. Ogidiama, Oghare Victor & Abu-Zahra, Mohammad R.M. & Shamim, Tariq, 2018. "Techno-economic analysis of a poly-generation solar-assisted chemical looping combustion power plant," Applied Energy, Elsevier, vol. 228(C), pages 724-735.
    7. Xu, Lei & Sun, Hongming & Li, Zhenshan & Cai, Ningsheng, 2016. "Experimental study of copper modified manganese ores as oxygen carriers in a dual fluidized bed reactor," Applied Energy, Elsevier, vol. 162(C), pages 940-947.
    8. Galinsky, Nathan & Mishra, Amit & Zhang, Jia & Li, Fanxing, 2015. "Ca1−xAxMnO3 (A=Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 157(C), pages 358-367.
    9. Ping Wang & Nicholas Means & Dushyant Shekhawat & David Berry & Mehrdad Massoudi, 2015. "Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review," Energies, MDPI, vol. 8(10), pages 1-31, September.
    10. Galinsky, Nathan & Sendi, Marwan & Bowers, Lindsay & Li, Fanxing, 2016. "CaMn1−xBxO3−δ (B=Al, V, Fe, Co, and Ni) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 174(C), pages 80-87.
    11. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    12. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    13. Wang, Zhe & Fan, Weiyu & Zhang, Guangqing & Dong, Shuang, 2016. "Exergy analysis of methane cracking thermally coupled with chemical looping combustion for hydrogen production," Applied Energy, Elsevier, vol. 168(C), pages 1-12.
    14. Haider, S.K. & Azimi, G. & Duan, L. & Anthony, E.J. & Patchigolla, K. & Oakey, J.E. & Leion, H. & Mattisson, T. & Lyngfelt, A., 2016. "Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation," Applied Energy, Elsevier, vol. 163(C), pages 41-50.
    15. Mendiara, T. & García-Labiano, F. & Abad, A. & Gayán, P. & de Diego, L.F. & Izquierdo, M.T. & Adánez, J., 2018. "Negative CO2 emissions through the use of biofuels in chemical looping technology: A review," Applied Energy, Elsevier, vol. 232(C), pages 657-684.
    16. Neal, Luke & Shafiefarhood, Arya & Li, Fanxing, 2015. "Effect of core and shell compositions on MeOx@LaySr1−yFeO3 core–shell redox catalysts for chemical looping reforming of methane," Applied Energy, Elsevier, vol. 157(C), pages 391-398.
    17. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    18. Deng, Guixian & Li, Kongzhai & Zhang, Guifang & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Wang, Hua, 2019. "Enhanced performance of red mud-based oxygen carriers by CuO for chemical looping combustion of methane," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    19. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    20. Kuang, Cao & Wang, Shuzhong & Luo, Ming & Cai, Jianjun & Zhao, Jun, 2020. "Investigation of CuO-based oxygen carriers modified by three different ores in chemical looping combustion with solid fuels," Renewable Energy, Elsevier, vol. 154(C), pages 937-948.
    21. Siriwardane, Ranjani & Benincosa, William & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier," Applied Energy, Elsevier, vol. 183(C), pages 1550-1564.
    22. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    23. Chen, Liangyong & Bao, Jinhua & Kong, Liang & Combs, Megan & Nikolic, Heather S. & Fan, Zhen & Liu, Kunlei, 2017. "Activation of ilmenite as an oxygen carrier for solid-fueled chemical looping combustion," Applied Energy, Elsevier, vol. 197(C), pages 40-51.

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