IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v236y2019icp1125-1137.html
   My bibliography  Save this article

Fast pyrolysis of lignins with different molecular weight: Experiments and modelling

Author

Listed:
  • Marathe, P.S.
  • Westerhof, R.J.M.
  • Kersten, S.R.A.

Abstract

Lignins with number average molecular weights between 350 Da and 1900 Da were characterised and subsequently pyrolysed in a screen-heater at pressures of 500 Pa and 105 Pa between 425 °C and 793 °C. Upwards of 530 °C, the temperature turned out to have only a minor influence on the yields and composition of the oils produced. Clear trends were observed as a function of the molecular weight and pressure – (1) at increasing molecular weight of the lignin, the oil yield decreases while yields of char and gas increase, (2) the molecular weight of the oil is lower for oils produced at 105 Pa as compared to the ones obtained at 500 Pa, (3) above a certain molecular weight of the lignins, ∼400 Da for 105 Pa and ∼800 Da for 500 Pa, the molecular weight of the oil becomes independent of the molecular weight of the lignin. A mathematical model has been developed, which includes three concurrently occurring processes, viz. cracking and polymerisation reactions and removal, hence mass transport, of unconverted lignin and reaction products from the reaction zone. This model can describe all the trends observed experimentally and provides, after parametrisation, reasonable qualitative predictions of the yield and molecular weight of the oils. Knowledge of the role of the interplay between mass transport and chemistry in the pyrolysis process is further accumulating, and from this the development of lignin valorisation can avail. For instance, it has become clear that in the pyrolysis process the molecular weight of lignin oil, which is an important characteristic for the upgrading of the oil to chemicals and/or fuels, can be steered with the pressure.

Suggested Citation

  • Marathe, P.S. & Westerhof, R.J.M. & Kersten, S.R.A., 2019. "Fast pyrolysis of lignins with different molecular weight: Experiments and modelling," Applied Energy, Elsevier, vol. 236(C), pages 1125-1137.
    • Handle: RePEc:eee:appene:v:236:y:2019:i:c:p:1125-1137
    DOI: 10.1016/j.apenergy.2018.12.058
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918318750
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.12.058?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
    2. Collett, James R. & Billing, Justin M. & Meyer, Pimphan A. & Schmidt, Andrew J. & Remington, A. Brook & Hawley, Erik R. & Hofstad, Beth A. & Panisko, Ellen A. & Dai, Ziyu & Hart, Todd R. & Santosa, Da, 2019. "Renewable diesel via hydrothermal liquefaction of oleaginous yeast and residual lignin from bioconversion of corn stover," Applied Energy, Elsevier, vol. 233, pages 840-853.
    3. Lou, Rui & Wu, Shu-bin, 2011. "Products properties from fast pyrolysis of enzymatic/mild acidolysis lignin," Applied Energy, Elsevier, vol. 88(1), pages 316-322, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Haowei & Ma, Hongwei & Zhao, Weijie & Li, Xuehui & Long, Jinxing, 2019. "Upgrading lignin bio-oil for oxygen-containing fuel production using Ni/MgO: Effect of the catalyst calcination temperature," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    2. Guzelciftci, Begum & Park, Ki-Bum & Kim, Joo-Sik, 2020. "Production of phenol-rich bio-oil via a two-stage pyrolysis of wood," Energy, Elsevier, vol. 200(C).
    3. Jalalifar, Salman & Masoudi, Mojtaba & Abbassi, Rouzbeh & Garaniya, Vikram & Ghiji, Mohammadmahdi & Salehi, Fatemeh, 2020. "A hybrid SVR-PSO model to predict a CFD-based optimised bubbling fluidised bed pyrolysis reactor," Energy, Elsevier, vol. 191(C).
    4. Huang, Youwang & Wang, Haiyong & Zhang, Xinghua & Zhang, Qi & Wang, Chenguang & Ma, Longlong, 2022. "Accurate prediction of chemical exergy of technical lignins for exergy-based assessment on sustainable utilization processes," Energy, Elsevier, vol. 243(C).
    5. Poveda-Giraldo, Jhonny Alejandro & Solarte-Toro, Juan Camilo & Cardona Alzate, Carlos Ariel, 2021. "The potential use of lignin as a platform product in biorefineries: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    6. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    7. Fan, Liangliang & Ruan, Roger & Li, Jun & Ma, Longlong & Wang, Chenguang & Zhou, Wenguang, 2020. "Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite," Applied Energy, Elsevier, vol. 263(C).
    8. Mayank Patel & Nick Hill & Charles A. Mullen & Sampath Gunukula & William J. DeSisto, 2020. "Fast Pyrolysis of Lignin Pretreated with Magnesium Formate and Magnesium Hydroxide," Energies, MDPI, vol. 13(19), pages 1-10, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    2. Long, Jinxing & Xu, Ying & Wang, Tiejun & Yuan, Zhengqiu & Shu, Riyang & Zhang, Qi & Ma, Longlong, 2015. "Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination," Applied Energy, Elsevier, vol. 141(C), pages 70-79.
    3. Xiaobo Wang & Anqi Liu & Zengli Zhao & Haibin Li, 2020. "Experimental and Model Study on Raw Biomass Gasification Syngas Conditioning in a Molten NaOH-Na 2 CO 3 Mixture," Energies, MDPI, vol. 13(14), pages 1-16, July.
    4. Chen, Xinyang & Cai, Di & Yang, Yumiao & Sun, Yuhang & Wang, Binhui & Yao, Zhitong & Jin, Meiqing & Liu, Jie & Reinmöller, Markus & Badshah, Syed Lal & Magdziarz, Aneta, 2023. "Pyrolysis kinetics of bio-based polyurethane: Evaluating the kinetic parameters, thermodynamic parameters, and complementary product gas analysis using TG/FTIR and TG/GC-MS," Renewable Energy, Elsevier, vol. 205(C), pages 490-498.
    5. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
    6. Fan, Liangliang & Ruan, Roger & Li, Jun & Ma, Longlong & Wang, Chenguang & Zhou, Wenguang, 2020. "Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite," Applied Energy, Elsevier, vol. 263(C).
    7. Lou, Rui & Wu, Shubin & Lv, Gaojin & Yang, Qing, 2012. "Energy and resource utilization of deinking sludge pyrolysis," Applied Energy, Elsevier, vol. 90(1), pages 46-50.
    8. Wei, Juntao & Guo, Qinghua & Ding, Lu & Yoshikawa, Kunio & Yu, Guangsuo, 2017. "Synergy mechanism analysis of petroleum coke and municipal solid waste (MSW)-derived hydrochar co-gasification," Applied Energy, Elsevier, vol. 206(C), pages 1354-1363.
    9. Liu, Yingzu & He, Yong & Wang, Zhihua & Xia, Jun & Wan, Kaidi & Whiddon, Ronald & Cen, Kefa, 2018. "Characteristics of alkali species release from a burning coal/biomass blend," Applied Energy, Elsevier, vol. 215(C), pages 523-531.
    10. Zhang, Yuming & Yao, Meiqin & Gao, Shiqiu & Sun, Guogang & Xu, Guangwen, 2015. "Reactivity and kinetics for steam gasification of petroleum coke blended with black liquor in a micro fluidized bed," Applied Energy, Elsevier, vol. 160(C), pages 820-828.
    11. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    12. Zhang, Yuming & Yu, Deping & Li, Wangliang & Gao, Shiqiu & Xu, Guangwen & Zhou, Huaqun & Chen, Jing, 2013. "Fundamental study of cracking gasification process for comprehensive utilization of vacuum residue," Applied Energy, Elsevier, vol. 112(C), pages 1318-1325.
    13. SundarRajan, P. & Gopinath, K.P. & Arun, J. & GracePavithra, K. & Adithya Joseph, A. & Manasa, S., 2021. "Insights into valuing the aqueous phase derived from hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    14. Zhang, Xinghua & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Huang, Xiaoming & Yu, Yuxiao, 2013. "Production of cyclohexane from lignin degradation compounds over Ni/ZrO2–SiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 533-538.
    15. Zhao, Na & Li, Bao-Xia, 2016. "The effect of sodium chloride on the pyrolysis of rice husk," Applied Energy, Elsevier, vol. 178(C), pages 346-352.
    16. Chen, Hao & Su, Xin & He, Jingjing & Zhang, Peng & Xu, Hongming & Zhou, Chenglong, 2021. "Investigation on combustion characteristics of cyclopentanol/diesel fuel blends in an optical engine," Renewable Energy, Elsevier, vol. 167(C), pages 811-829.
    17. Ouyang, Denghao & Wang, Fangqian & Hong, Jinpeng & Gao, Daihong & Zhao, Xuebing, 2021. "Ferricyanide and vanadyl (V) mediated electron transfer for converting lignin to electricity by liquid flow fuel cell with power density reaching 200 mW/cm2," Applied Energy, Elsevier, vol. 304(C).
    18. Yue Cao & Yongsheng Sun & Peng Gao & Wenbo Li, 2023. "Utilization of Waste Straw Biomass in Suspension Magnetization Roasting of Refractory Iron Ore: Iron Recovery, Gas Analysis and Roasted Product Characterization," Sustainability, MDPI, vol. 15(22), pages 1-18, November.
    19. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    20. Li, Bingshuo & Yang, Tianhua & Li, Rundong & Kai, Xingping, 2020. "Co-generation of liquid biofuels from lignocellulose by integrated biochemical and hydrothermal liquefaction process," Energy, Elsevier, vol. 200(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:236:y:2019:i:c:p:1125-1137. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.