IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v213y2018icp285-292.html
   My bibliography  Save this article

Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion

Author

Listed:
  • Zhang, Hao
  • Liu, Xiangyu
  • Hong, Hui
  • Jin, Hongguang

Abstract

Chemical-looping combustion (CLC) is already treated as a promising way to capture CO2 in the utilization of fossil fuels. The most used reactors for the CLC are fluidized-beds, in which the fuel conversion and the conversion of fuel to CO2 is determined by the bed height. Here in this study, the CLC in an advanced 10 kW honeycomb reactor is studied by using natural gas as the fuel and Fe2O3 as the oxygen carrier. In the honeycomb reactor, a honeycomb chamber consisted by the oxygen carrier is employed to enhance the contact area and the disturbance between the fuel gas and the oxygen carrier. Both of these two enhancement are benefit for achieving a high CH4 conversion and a high conversion of CH4 to CO2. The experiment results show that three stages of Fe2O3 to Fe3O4, Fe3O4 to FeO and FeO to Fe are occurred in sequence during the reduction reaction of Fe2O3 and CH4 in the honeycomb reactor. The behaviors and the relationships for these complicated reactions, the oxygen transfer rate, the CH4 conversion and the conversion of CH4 to CO2 at different stages are further experimentally studied. Additionally, to increasing the conversion of CH4 to CO2 in the continuous operation, the characteristics for the honeycomb reactor in redox cycles are also experimentally investigated. Our study here would be expected to provide a new method for developing the energy and environment compatible systems.

Suggested Citation

  • Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
  • Handle: RePEc:eee:appene:v:213:y:2018:i:c:p:285-292
    DOI: 10.1016/j.apenergy.2018.01.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918300382
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2018.01.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Liangyong & Kong, Liang & Bao, Jinhua & Combs, Megan & Nikolic, Heather S. & Fan, Zhen & Liu, Kunlei, 2017. "Experimental evaluations of solid-fueled pressurized chemical looping combustion – The effects of pressure, solid fuel and iron-based oxygen carriers," Applied Energy, Elsevier, vol. 195(C), pages 1012-1022.
    2. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    3. Zhang, Yongxing & Doroodchi, Elham & Moghtaderi, Behdad, 2014. "Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2," Applied Energy, Elsevier, vol. 113(C), pages 1916-1923.
    4. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
    5. Han, Lu & Bollas, George M., 2016. "Chemical-looping combustion in a reverse-flow fixed bed reactor," Energy, Elsevier, vol. 102(C), pages 669-681.
    6. Hamers, H.P. & Romano, M.C. & Spallina, V. & Chiesa, P. & Gallucci, F. & van Sint Annaland, M., 2015. "Boosting the IGCLC process efficiency by optimizing the desulfurization step," Applied Energy, Elsevier, vol. 157(C), pages 422-432.
    7. Hamers, H.P. & Gallucci, F. & Cobden, P.D. & Kimball, E. & van Sint Annaland, M., 2014. "CLC in packed beds using syngas and CuO/Al2O3: Model description and experimental validation," Applied Energy, Elsevier, vol. 119(C), pages 163-172.
    8. Middleton, Richard S. & Eccles, Jordan K., 2013. "The complex future of CO2 capture and storage: Variable electricity generation and fossil fuel power," Applied Energy, Elsevier, vol. 108(C), pages 66-73.
    9. Tong, Andrew & Bayham, Samuel & Kathe, Mandar V. & Zeng, Liang & Luo, Siwei & Fan, Liang-Shih, 2014. "Iron-based syngas chemical looping process and coal-direct chemical looping process development at Ohio State University," Applied Energy, Elsevier, vol. 113(C), pages 1836-1845.
    10. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    11. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
    12. Thon, Andreas & Kramp, Marvin & Hartge, Ernst-Ulrich & Heinrich, Stefan & Werther, Joachim, 2014. "Operational experience with a system of coupled fluidized beds for chemical looping combustion of solid fuels using ilmenite as oxygen carrier," Applied Energy, Elsevier, vol. 118(C), pages 309-317.
    13. Ishida, Masaru & Jin, Hongguang, 1994. "A new advanced power-generation system using chemical-looping combustion," Energy, Elsevier, vol. 19(4), pages 415-422.
    14. Li, H. & Yan, J. & Yan, J. & Anheden, M., 2009. "Impurity impacts on the purification process in oxy-fuel combustion based CO2 capture and storage system," Applied Energy, Elsevier, vol. 86(2), pages 202-213, February.
    15. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Yiyuan & Zhu, Qunzhi & Zhang, Tao & Yan, Xuefeng & Duan, Rui, 2020. "Analysis of chemical-looping hydrogen production and power generation system driven by solar energy," Renewable Energy, Elsevier, vol. 154(C), pages 863-874.
    2. Liu, Xiangyu & Zhang, Hao & Hong, Hui & Jin, Hongguang, 2020. "Experimental study on honeycomb reactor using methane via chemical looping cycle for solar syngas," Applied Energy, Elsevier, vol. 268(C).
    3. Liu, Xiangyu & Hong, Hui & Zhang, Hao & Cao, Yali & Qu, Wanjun & Jin, Hongguang, 2020. "Solar methanol by hybridizing natural gas chemical looping reforming with solar heat," Applied Energy, Elsevier, vol. 277(C).
    4. Liyan Sun & Junjie Lin & Dali Kong & Kun Luo & Jianren Fan, 2022. "Numerical Simulation of a 10 kW Gas-Fueled Chemical Looping Combustion Unit," Energies, MDPI, vol. 15(6), pages 1-11, March.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    2. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    3. Chang, F.C. & Liao, P.H. & Tsai, C.K. & Hsiao, M.C. & Paul Wang, H., 2014. "Chemical-looping combustion of syngas with nano CuO–NiO on chabazite," Applied Energy, Elsevier, vol. 113(C), pages 1731-1736.
    4. Huang, Liang & Tang, Mingchen & Fan, Maohong & Cheng, Hansong, 2015. "Density functional theory study on the reaction between hematite and methane during chemical looping process," Applied Energy, Elsevier, vol. 159(C), pages 132-144.
    5. Siriwardane, Ranjani & Benincosa, William & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier," Applied Energy, Elsevier, vol. 183(C), pages 1550-1564.
    6. Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    7. Medrano, J.A. & Potdar, I. & Melendez, J. & Spallina, V. & Pacheco-Tanaka, D.A. & van Sint Annaland, M. & Gallucci, F., 2018. "The membrane-assisted chemical looping reforming concept for efficient H2 production with inherent CO2 capture: Experimental demonstration and model validation," Applied Energy, Elsevier, vol. 215(C), pages 75-86.
    8. Xiaosong Zhang & Sheng Li & Hongguang Jin, 2014. "A Polygeneration System Based on Multi-Input Chemical Looping Combustion," Energies, MDPI, vol. 7(11), pages 1-12, November.
    9. Galinsky, Nathan & Mishra, Amit & Zhang, Jia & Li, Fanxing, 2015. "Ca1−xAxMnO3 (A=Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 157(C), pages 358-367.
    10. Ping Wang & Nicholas Means & Dushyant Shekhawat & David Berry & Mehrdad Massoudi, 2015. "Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review," Energies, MDPI, vol. 8(10), pages 1-31, September.
    11. Galinsky, Nathan & Sendi, Marwan & Bowers, Lindsay & Li, Fanxing, 2016. "CaMn1−xBxO3−δ (B=Al, V, Fe, Co, and Ni) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 174(C), pages 80-87.
    12. Xu, Lei & Sun, Hongming & Li, Zhenshan & Cai, Ningsheng, 2016. "Experimental study of copper modified manganese ores as oxygen carriers in a dual fluidized bed reactor," Applied Energy, Elsevier, vol. 162(C), pages 940-947.
    13. Liu, Xiangyu & Hong, Hui & Zhang, Hao & Cao, Yali & Qu, Wanjun & Jin, Hongguang, 2020. "Solar methanol by hybridizing natural gas chemical looping reforming with solar heat," Applied Energy, Elsevier, vol. 277(C).
    14. Liu, Xiangyu & Zhang, Hao & Hong, Hui & Jin, Hongguang, 2020. "Experimental study on honeycomb reactor using methane via chemical looping cycle for solar syngas," Applied Energy, Elsevier, vol. 268(C).
    15. Bayham, Samuel & McGiveron, Omar & Tong, Andrew & Chung, Elena & Kathe, Mandar & Wang, Dawei & Zeng, Liang & Fan, Liang-Shih, 2015. "Parametric and dynamic studies of an iron-based 25-kWth coal direct chemical looping unit using sub-bituminous coal," Applied Energy, Elsevier, vol. 145(C), pages 354-363.
    16. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    17. Mendiara, T. & García-Labiano, F. & Abad, A. & Gayán, P. & de Diego, L.F. & Izquierdo, M.T. & Adánez, J., 2018. "Negative CO2 emissions through the use of biofuels in chemical looping technology: A review," Applied Energy, Elsevier, vol. 232(C), pages 657-684.
    18. Cheng, Xianming & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Zhouhang & Long, Yanhui & Zheng, Min & Tian, Dong & Wang, Hua, 2018. "Enhanced performance of chemical looping combustion of methane by combining oxygen carriers via optimizing the stacking sequences," Applied Energy, Elsevier, vol. 230(C), pages 696-711.
    19. Cho, Won Chul & Lee, Jun Kyu & Nam, Gyeong Duk & Kim, Chang Hee & Cho, Hyun-Seok & Joo, Jong Hoon, 2019. "Degradation analysis of mixed ionic-electronic conductor-supported iron-oxide oxygen carriers for chemical-looping conversion of methane," Applied Energy, Elsevier, vol. 239(C), pages 644-657.
    20. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2017. "A reduced fidelity model for the rotary chemical looping combustion reactor," Applied Energy, Elsevier, vol. 190(C), pages 725-739.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:213:y:2018:i:c:p:285-292. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.