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Catalyst support effects on hydrogen spillover

Author

Listed:
  • Waiz Karim

    (Institute for Chemical and Bioengineering, ETH Zurich
    Laboratory for Micro and Nanotechnology, Paul Scherrer Institute
    Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute)

  • Clelia Spreafico

    (Nanoscale Simulations, ETH Zurich)

  • Armin Kleibert

    (Swiss Light Source, Paul Scherrer Institute)

  • Jens Gobrecht

    (Laboratory for Micro and Nanotechnology, Paul Scherrer Institute)

  • Joost VandeVondele

    (Nanoscale Simulations, ETH Zurich)

  • Yasin Ekinci

    (Laboratory for Micro and Nanotechnology, Paul Scherrer Institute)

  • Jeroen A. van Bokhoven

    (Institute for Chemical and Bioengineering, ETH Zurich
    Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute)

Abstract

The mechanism of hydrogen spillover is described using a precisely nanofabricated model system, explaining why it is slower on an aluminum oxide catalyst support than on a titanium oxide catalyst support.

Suggested Citation

  • Waiz Karim & Clelia Spreafico & Armin Kleibert & Jens Gobrecht & Joost VandeVondele & Yasin Ekinci & Jeroen A. van Bokhoven, 2017. "Catalyst support effects on hydrogen spillover," Nature, Nature, vol. 541(7635), pages 68-71, January.
    • Handle: RePEc:nat:nature:v:541:y:2017:i:7635:d:10.1038_nature20782
    DOI: 10.1038/nature20782
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    Cited by:

    1. Mingwu Tan & Yanling Yang & Ying Yang & Jiali Chen & Zhaoxia Zhang & Gang Fu & Jingdong Lin & Shaolong Wan & Shuai Wang & Yong Wang, 2022. "Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Zhang, J. & He, L. & Yao, Y. & Zhou, X.J. & Yu, L.P. & Lu, X.Z. & Zhou, D.W., 2020. "Catalytic effect and mechanism of NiCu solid solutions on hydrogen storage properties of MgH2," Renewable Energy, Elsevier, vol. 154(C), pages 1229-1239.
    3. Kazuki Shun & Kohsuke Mori & Takumi Kidawara & Satoshi Ichikawa & Hiromi Yamashita, 2024. "Heteroatom doping enables hydrogen spillover via H+/e− diffusion pathways on a non-reducible metal oxide," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Qiaoxi Liu & Wenjie Xu & Hao Huang & Hongwei Shou & Jingxiang Low & Yitao Dai & Wanbing Gong & Youyou Li & Delong Duan & Wenqing Zhang & Yawen Jiang & Guikai Zhang & Dengfeng Cao & Kecheng Wei & Ran L, 2024. "Spectroscopic visualization of reversible hydrogen spillover between palladium and metal–organic frameworks toward catalytic semihydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Chengsheng Yang & Sicong Ma & Yongmei Liu & Lihua Wang & Desheng Yuan & Wei-Peng Shao & Lunjia Zhang & Fan Yang & Tiejun Lin & Hongxin Ding & Heyong He & Zhi-Pan Liu & Yong Cao & Yifeng Zhu & Xinhe Ba, 2024. "Homolytic H2 dissociation for enhanced hydrogenation catalysis on oxides," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Jaianth Vijayakumar & Tatiana M. Savchenko & David M. Bracher & Gunnar Lumbeeck & Armand Béché & Jo Verbeeck & Štefan Vajda & Frithjof Nolting & C.A.F. Vaz & Armin Kleibert, 2023. "Absence of a pressure gap and atomistic mechanism of the oxidation of pure Co nanoparticles," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Chen, Jiateng & Xu, Le & Shen, Boxiong, 2024. "Recent advances in tandem electrocatalysis of carbon dioxide: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    8. Xiao-Jue Bai & Caoyu Yang & Zhiyong Tang, 2024. "Enabling long-distance hydrogen spillover in nonreducible metal-organic frameworks for catalytic reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    9. Jinqi Xiong & Shanjun Mao & Qian Luo & Honghui Ning & Bing Lu & Yanling Liu & Yong Wang, 2024. "Mediating trade-off between activity and selectivity in alkynes semi-hydrogenation via a hydrophilic polar layer," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Zhenglong Fan & Fan Liao & Yujin Ji & Yang Liu & Hui Huang & Dan Wang & Kui Yin & Haiwei Yang & Mengjie Ma & Wenxiang Zhu & Meng Wang & Zhenhui Kang & Youyong Li & Mingwang Shao & Zhiwei Hu & Qi Shao, 2022. "Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Zhi Wen Chen & Jian Li & Pengfei Ou & Jianan Erick Huang & Zi Wen & LiXin Chen & Xue Yao & GuangMing Cai & Chun Cheng Yang & Chandra Veer Singh & Qing Jiang, 2024. "Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    12. Xuemei Wu & Chengwei Wang & Shengying Zhao & Yang Wang & Tao Zhang & Jie Yao & Weizhe Gao & Baizhang Zhang & Taiki Arakawa & Yingluo He & Fei Chen & Minghui Tan & Guohui Yang & Noritatsu Tsubaki, 2024. "Dual-engine-driven realizing high-yield synthesis of Para-Xylene directly from CO2-containing syngas," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    13. Zhida Gu & Mengke Li & Cheng Chen & Xinglong Zhang & Chengyang Luo & Yutao Yin & Ruifa Su & Suoying Zhang & Yu Shen & Yu Fu & Weina Zhang & Fengwei Huo, 2023. "Water-assisted hydrogen spillover in Pt nanoparticle-based metal–organic framework composites," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

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