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Implanting oxophilic metal in PtRu nanowires for hydrogen oxidation catalysis

Author

Listed:
  • Zhongliang Huang

    (Xiamen University)

  • Shengnan Hu

    (Xiamen University)

  • Mingzi Sun

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon)

  • Yong Xu

    (Chinese Academy of Sciences (CAS))

  • Shangheng Liu

    (Xiamen University)

  • Renjie Ren

    (Wuhan University)

  • Lin Zhuang

    (Wuhan University)

  • Ting-Shan Chan

    (National Synchrotron Radiation Research Center)

  • Zhiwei Hu

    (Max Planck Institute for Chemical Physics of Solids)

  • Tianyi Ding

    (Xiamen University)

  • Jing Zhou

    (Chinese Academy of Sciences)

  • Liangbin Liu

    (Xiamen University)

  • Mingmin Wang

    (Xiamen University)

  • Yu-Cheng Huang

    (National Yang Ming Chiao Tung University)

  • Na Tian

    (Xiamen University)

  • Lingzheng Bu

    (Xiamen University)

  • Bolong Huang

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon)

  • Xiaoqing Huang

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

Abstract

Bimetallic PtRu are promising electrocatalysts for hydrogen oxidation reaction in anion exchange membrane fuel cell, where the activity and stability are still unsatisfying. Here, PtRu nanowires were implanted with a series of oxophilic metal atoms (named as i-M-PR), significantly enhancing alkaline hydrogen oxidation reaction (HOR) activity and stability. With the dual doping of In and Zn atoms, the i-ZnIn-PR/C shows mass activity of 10.2 A mgPt+Ru−1 at 50 mV, largely surpassing that of commercial Pt/C (0.27 A mgPt−1) and PtRu/C (1.24 A mgPt+Ru−1). More importantly, the peak power density and specific power density are as high as 1.84 W cm−2 and 18.4 W mgPt+Ru−1 with a low loading (0.1 mg cm−2) anion exchange membrane fuel cell. Advanced experimental characterizations and theoretical calculations collectively suggest that dual doping with In and Zn atoms optimizes the binding strengths of intermediates and promotes CO oxidation, enhancing the HOR performances. This work deepens the understanding of developing novel alloy catalysts, which will attract immediate interest in materials, chemistry, energy and beyond.

Suggested Citation

  • Zhongliang Huang & Shengnan Hu & Mingzi Sun & Yong Xu & Shangheng Liu & Renjie Ren & Lin Zhuang & Ting-Shan Chan & Zhiwei Hu & Tianyi Ding & Jing Zhou & Liangbin Liu & Mingmin Wang & Yu-Cheng Huang & , 2024. "Implanting oxophilic metal in PtRu nanowires for hydrogen oxidation catalysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45369-x
    DOI: 10.1038/s41467-024-45369-x
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