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Customized reaction route for ruthenium oxide towards stabilized water oxidation in high-performance PEM electrolyzers

Author

Listed:
  • Zhaoping Shi

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Ji Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yibo Wang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Shiwei Liu

    (Chinese Academy of Sciences)

  • Jianbing Zhu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Jiahao Yang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Xian Wang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Jing Ni

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Zheng Jiang

    (Chinese Academy of Sciences
    Chinese Academy of Science)

  • Lijuan Zhang

    (Chinese Academy of Sciences
    Chinese Academy of Science)

  • Ying Wang

    (Chinese Academy of Sciences)

  • Changpeng Liu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Wei Xing

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Junjie Ge

    (Chinese Academy of Sciences
    University of Science and Technology of China)

Abstract

The poor stability of Ru-based acidic oxygen evolution (OER) electrocatalysts has greatly hampered their application in polymer electrolyte membrane electrolyzers (PEMWEs). Traditional understanding of performance degradation centered on influence of bias fails in describing the stability trend, calling for deep dive into the essential origin of inactivation. Here we uncover the decisive role of reaction route (including catalytic mechanism and intermediates binding strength) on operational stability of Ru-based catalysts. Using MRuOx (M = Ce4+, Sn4+, Ru4+, Cr4+) solid solution as structure model, we find the reaction route, thereby stability, can be customized by controlling the Ru charge. The screened SnRuOx thus exhibits orders of magnitude lifespan extension. A scalable PEMWE single cell using SnRuOx anode conveys an ever-smallest degradation rate of 53 μV h−1 during a 1300 h operation at 1 A cm−2.

Suggested Citation

  • Zhaoping Shi & Ji Li & Yibo Wang & Shiwei Liu & Jianbing Zhu & Jiahao Yang & Xian Wang & Jing Ni & Zheng Jiang & Lijuan Zhang & Ying Wang & Changpeng Liu & Wei Xing & Junjie Ge, 2023. "Customized reaction route for ruthenium oxide towards stabilized water oxidation in high-performance PEM electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36380-9
    DOI: 10.1038/s41467-023-36380-9
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    2. Yanrong Xue & Jiwu Zhao & Liang Huang & Ying-Rui Lu & Abdul Malek & Ge Gao & Zhongbin Zhuang & Dingsheng Wang & Cafer T. Yavuz & Xu Lu, 2023. "Stabilizing ruthenium dioxide with cation-anchored sulfate for durable oxygen evolution in proton-exchange membrane water electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Xinyu Ping & Yongduo Liu & Lixia Zheng & Yang Song & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Locking the lattice oxygen in RuO2 to stabilize highly active Ru sites in acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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