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Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites

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  • Tingting Zhu

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    ShanghaiTech University
    Jiangxi Normal University
    University of Chinese Academy of Sciences)

  • Jie Bie

    (Nanjing University
    Nanjing University)

  • Chengmin Ji

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    University of Chinese Academy of Sciences
    Fujian Science & Technology Innovation Laboratory for Optoelectric Information of China, Fuzhou)

  • Xinyuan Zhang

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    University of Chinese Academy of Sciences
    Fujian Science & Technology Innovation Laboratory for Optoelectric Information of China, Fuzhou)

  • Lina Li

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    Fujian Science & Technology Innovation Laboratory for Optoelectric Information of China, Fuzhou)

  • Xitao Liu

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    Fujian Science & Technology Innovation Laboratory for Optoelectric Information of China, Fuzhou)

  • Xiao-Ying Huang

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou)

  • Wei Fa

    (Nanjing University)

  • Shuang Chen

    (Nanjing University
    Nanjing University)

  • Junhua Luo

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
    ShanghaiTech University
    Jiangxi Normal University
    University of Chinese Academy of Sciences)

Abstract

Circular polarized light-dependent anomalous bulk photovoltaic effect - a steady anomalous photovoltaic current can be manipulated by changing the light helicity, is an increasingly interesting topic in contexts ranging from physics to chemistry. Herein, circular polarized light-dependent anomalous bulk photovoltaic effect is presented in achiral hybrid perovskites, (4-AMP)BiI5 (ABI, 4-AMP is 4-(aminomethyl)piperidinium), breaking conventional realization that it can only happen in chiral species. Achiral hybrid perovskite ABI crystallizes in chiroptical-active asymmetric point group m (Cs), showing an anomalous bulk photovoltaic effect with giant photovoltage of 25 V, as well as strong circular polarized light - sensitive properties. Significantly, conspicuous circular polarized light-dependent anomalous bulk photovoltaic effect is reflected in the large degree of dependence of anomalous bulk photovoltaic effect on left-and right-CPL helicity, which is associated with left and right-handed screw optical axes of ABI. Such degree of dependence is demonstrated by a large asymmetry factor of 0.24, which almost falls around the highest value of hybrid perovskites. These unprecedented results may provide a perspective to develop opto-spintronic functionalities in hybrid perovskites.

Suggested Citation

  • Tingting Zhu & Jie Bie & Chengmin Ji & Xinyuan Zhang & Lina Li & Xitao Liu & Xiao-Ying Huang & Wei Fa & Shuang Chen & Junhua Luo, 2022. "Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35441-9
    DOI: 10.1038/s41467-022-35441-9
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    References listed on IDEAS

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    1. M. Nakamura & S. Horiuchi & F. Kagawa & N. Ogawa & T. Kurumaji & Y. Tokura & M. Kawasaki, 2017. "Shift current photovoltaic effect in a ferroelectric charge-transfer complex," Nature Communications, Nature, vol. 8(1), pages 1-6, December.
    2. Christopher Eames & Jarvist M. Frost & Piers R. F. Barnes & Brian C. O’Regan & Aron Walsh & M. Saiful Islam, 2015. "Ionic transport in hybrid lead iodide perovskite solar cells," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    3. David S. Knoche & Matthias Steimecke & Yeseul Yun & Lutz Mühlenbein & Akash Bhatnagar, 2021. "Anomalous circular bulk photovoltaic effect in BiFeO3 thin films with stripe-domain pattern," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    4. Chao Chen & Liang Gao & Wanru Gao & Cong Ge & Xinyuan Du & Zha Li & Ying Yang & Guangda Niu & Jiang Tang, 2019. "Circularly polarized light detection using chiral hybrid perovskite," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
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