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Rapid and efficient hydrogen clathrate hydrate formation in confined nanospace

Author

Listed:
  • Judit Farrando-Perez

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica-Instituto Universitario de Materiales, Universidad de Alicante)

  • Rafael Balderas-Xicohtencatl

    (Spallation Neutron Source, Oak Ridge National Laboratory)

  • Yongqiang Cheng

    (Spallation Neutron Source, Oak Ridge National Laboratory)

  • Luke Daemen

    (Spallation Neutron Source, Oak Ridge National Laboratory)

  • Carlos Cuadrado-Collados

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica-Instituto Universitario de Materiales, Universidad de Alicante)

  • Manuel Martinez-Escandell

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica-Instituto Universitario de Materiales, Universidad de Alicante)

  • Anibal J. Ramirez-Cuesta

    (Spallation Neutron Source, Oak Ridge National Laboratory)

  • Joaquin Silvestre-Albero

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica-Instituto Universitario de Materiales, Universidad de Alicante)

Abstract

Clathrate hydrates are crystalline solids characterized by their ability to accommodate large quantities of guest molecules. Although CH4 and CO2 are the traditional guests found in natural systems, incorporating smaller molecules (e.g., H2) is challenging due to the need to apply higher pressures to stabilize the hydrogen-bonded network. Another critical limitation of hydrates is the slow nucleation and growth kinetics. Here, we show that specially designed activated carbon materials can surpass these obstacles by acting as nanoreactors promoting the nucleation and growth of H2 hydrates. The confinement effects in the inner cavities promote the massive growth of hydrogen hydrates at moderate temperatures, using pure water, with extremely fast kinetics and much lower pressures than the bulk system.

Suggested Citation

  • Judit Farrando-Perez & Rafael Balderas-Xicohtencatl & Yongqiang Cheng & Luke Daemen & Carlos Cuadrado-Collados & Manuel Martinez-Escandell & Anibal J. Ramirez-Cuesta & Joaquin Silvestre-Albero, 2022. "Rapid and efficient hydrogen clathrate hydrate formation in confined nanospace," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33674-2
    DOI: 10.1038/s41467-022-33674-2
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    References listed on IDEAS

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    1. Toshihiko Fujimori & Aarón Morelos-Gómez & Zhen Zhu & Hiroyuki Muramatsu & Ryusuke Futamura & Koki Urita & Mauricio Terrones & Takuya Hayashi & Morinobu Endo & Sang Young Hong & Young Chul Choi & Davi, 2013. "Conducting linear chains of sulphur inside carbon nanotubes," Nature Communications, Nature, vol. 4(1), pages 1-8, October.
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    1. Kong, Yaning & Yu, Honglin & Liu, Mengqi & Zhang, Guodong & Wang, Fei, 2024. "Ultra-rapid formation of mixed H2/DIOX/THF hydrate under low driving force: Important insight for hydrate-based hydrogen storage," Applied Energy, Elsevier, vol. 362(C).

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