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Photo-tailored heterocrystalline covalent organic framework membranes for organics separation

Author

Listed:
  • Jinqiu Yuan

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Xinda You

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Niaz Ali Khan

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Runlai Li

    (National University of Singapore)

  • Runnan Zhang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Zhejiang Institute of Tianjin University)

  • Jianliang Shen

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Li Cao

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Mengying Long

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    International Campus of Tianjin University)

  • Yanan Liu

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Zijian Xu

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Hong Wu

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Tianjin University)

  • Zhongyi Jiang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Zhejiang Institute of Tianjin University
    International Campus of Tianjin University)

Abstract

Organics separation for purifying and recycling environment-detrimental solvents is essential to sustainable chemical industries. Covalent organic framework (COF) membranes hold great promise in affording precise and fast organics separation. Nonetheless, how to well coordinate facile processing—high crystalline structure—high separation performance remains a critical issue and a grand challenge. Herein, we propose a concept of heterocrystalline membrane which comprises high-crystalline regions and low-crystalline regions. The heterocrystalline COF membranes are fabricated by a two-step procedure, i.e., dark reaction for the construction of high-crystalline regions followed by photo reaction for the construction of low-crystalline regions, thus linking the high-crystalline regions tightly and flexibly, blocking the defect in high-crystalline regions. Accordingly, the COF membrane exhibits sharp molecular sieving properties with high organic solvent permeance up to 44-times higher than the state-of-the-art membranes.

Suggested Citation

  • Jinqiu Yuan & Xinda You & Niaz Ali Khan & Runlai Li & Runnan Zhang & Jianliang Shen & Li Cao & Mengying Long & Yanan Liu & Zijian Xu & Hong Wu & Zhongyi Jiang, 2022. "Photo-tailored heterocrystalline covalent organic framework membranes for organics separation," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31361-w
    DOI: 10.1038/s41467-022-31361-w
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    References listed on IDEAS

    as
    1. David S. Sholl & Ryan P. Lively, 2016. "Seven chemical separations to change the world," Nature, Nature, vol. 532(7600), pages 435-437, April.
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    Cited by:

    1. Hao Yang & Jinhui Xu & Hui Cao & Jie Wu & Dan Zhao, 2023. "Recovery of homogeneous photocatalysts by covalent organic framework membranes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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