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Keeping sight of copper in single-atom catalysts for electrochemical carbon dioxide reduction

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  • Charles E. Creissen

    (Collège de France)

  • Marc Fontecave

    (Collège de France)

Abstract

Carbon dioxide can be electrochemically converted into valuable multi-carbon products using Cu-based single-atom catalysts. However, transient cluster formation, which is undetectable using ex-situ techniques, may be responsible for C2+ products. Here we discuss these observations to highlight the need for operando characterisation when defining active sites.

Suggested Citation

  • Charles E. Creissen & Marc Fontecave, 2022. "Keeping sight of copper in single-atom catalysts for electrochemical carbon dioxide reduction," Nature Communications, Nature, vol. 13(1), pages 1-4, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30027-x
    DOI: 10.1038/s41467-022-30027-x
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    1. Zhe Weng & Yueshen Wu & Maoyu Wang & Jianbing Jiang & Ke Yang & Shengjuan Huo & Xiao-Feng Wang & Qing Ma & Gary W. Brudvig & Victor S. Batista & Yongye Liang & Zhenxing Feng & Hailiang Wang, 2018. "Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    2. Haiping Xu & Dominic Rebollar & Haiying He & Lina Chong & Yuzi Liu & Cong Liu & Cheng-Jun Sun & Tao Li & John V. Muntean & Randall E. Winans & Di-Jia Liu & Tao Xu, 2020. "Highly selective electrocatalytic CO2 reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper," Nature Energy, Nature, vol. 5(8), pages 623-632, August.
    3. Wen Ju & Alexander Bagger & Guang-Ping Hao & Ana Sofia Varela & Ilya Sinev & Volodymyr Bon & Beatriz Roldan Cuenya & Stefan Kaskel & Jan Rossmeisl & Peter Strasser, 2017. "Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    4. Sharon Mitchell & Javier Pérez-Ramírez, 2020. "Single atom catalysis: a decade of stunning progress and the promise for a bright future," Nature Communications, Nature, vol. 11(1), pages 1-3, December.
    5. Yi Xu & Fengwang Li & Aoni Xu & Jonathan P. Edwards & Sung-Fu Hung & Christine M. Gabardo & Colin P. O’Brien & Shijie Liu & Xue Wang & Yuhang Li & Joshua Wicks & Rui Kai Miao & Yuan Liu & Jun Li & Jia, 2021. "Low coordination number copper catalysts for electrochemical CO2 methanation in a membrane electrode assembly," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    6. Kun Zhao & Xiaowa Nie & Haozhi Wang & Shuo Chen & Xie Quan & Hongtao Yu & Wonyong Choi & Guanghui Zhang & Bupmo Kim & Jingguang G. Chen, 2020. "Selective electroreduction of CO2 to acetone by single copper atoms anchored on N-doped porous carbon," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
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