IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i2p1245-d1030105.html
   My bibliography  Save this article

Hyperbranched Dithiocarbamate-Modified Biochar: A Promising Adsorbent for Selective Removal of Pb(II) from Wastewater

Author

Listed:
  • Xin Xie

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

  • Jiangtao He

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

  • Jianhong Huang

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

  • Jie Li

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

  • Yingjie Li

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

  • Senlin Tian

    (Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)

Abstract

Herein, dithiocarbamate-modified biochar (BC-HDTC) was successfully synthesized with nitric acid (HNO 3 ), thionyl chloride (SOCl 2 ), branched PEI and carbon disulfide (CS 2 ). The effective anchoring of amine and dithiocarbamate groups onto the surface of the biochar was proven by SEM, FTIR, XPS, N2 adsorption–desorption experiment. The batch experiments demonstrated BC-HDTC can selectively remove 98% Pb(II) within multi-metals solution when pH = 5, T = 30 °C. The impact of variations on the BC-HDTC were researched (pH, contact duration, Pb(II) original concentration).The sorption kinetics (pseudo-first-order, pseudo-second-order, intra-particle diffusion model) and isotherm modeling (Langmuir, Freundlich, and tempkin models) of Pb(II) on BC-HDTC were investigated. The adsorption process was depicted to attain equilibrium in less than 20 min and to fit the Langmuir isotherms and pseudo-2nd-order kinetics satisfactorily. The complexation of functional groups of HDTC (amine/imine and dithiocarbamate) with Pb(II) as well as the ion exchange between Na(I) and Pb(II) are the main adsorption mechanisms. Pb(II) onto BC-HDTC was endothermic and spontaneous, according to thermodynamic parameters. After 4 consecutive adsorption-desorption cycles, Pb removal efficiency of BC- HDTC remained over 90%. This work revealed the significant potential for Pb(II) contamination of BC-HDTC, a valuable and reusable adsorbent.

Suggested Citation

  • Xin Xie & Jiangtao He & Jianhong Huang & Jie Li & Yingjie Li & Senlin Tian, 2023. "Hyperbranched Dithiocarbamate-Modified Biochar: A Promising Adsorbent for Selective Removal of Pb(II) from Wastewater," Sustainability, MDPI, vol. 15(2), pages 1-17, January.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:2:p:1245-:d:1030105
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/2/1245/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/15/2/1245/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ying, Zhi & Geng, Zhen & Zheng, Xiaoyuan & Dou, Binlin & Cui, Guomin, 2022. "Improving water electrolysis assisted by anodic biochar oxidation for clean hydrogen production," Energy, Elsevier, vol. 238(PB).
    2. Hatem Abushammala & Muhammad Adil Masood & Salma Taqi Ghulam & Jia Mao, 2023. "On the Conversion of Paper Waste and Rejects into High-Value Materials and Energy," Sustainability, MDPI, vol. 15(8), pages 1-21, April.
    3. Yan, Xiaopeng & Chen, Baijin, 2021. "Analysis of a novel energy-efficient system with 3-D vertical structure for hydraulic press," Energy, Elsevier, vol. 218(C).
    4. Shangdiar, Sumarlin & Lin, Yuan-Chung & Cheng, Pei-Cheng & Chou, Feng-Chih & Wu, Wen-Ding, 2021. "Development of biochar from the refuse derived fuel (RDF) through organic / inorganic sludge mixed with rice straw and coconut shell," Energy, Elsevier, vol. 215(PB).
    5. Karolina Barčauskaitė & Olga Anne & Ieva Mockevičienė & Regina Repšienė & Gintaras Šiaudinis & Danutė Karčauskienė, 2023. "Determination of Heavy Metals Immobilization by Chemical Fractions in Contaminated Soil Amended with Biochar," Sustainability, MDPI, vol. 15(11), pages 1-15, May.
    6. Motasem Y. D. Alazaiza & Ahmed Albahnasawi & Murat Eyvaz & Tahra Al Maskari & Dia Eddin Nassani & Salem S. Abu Amr & Mohammed Shadi S. Abujazar & Mohammed J. K. Bashir, 2023. "An Overview of Green Bioprocessing of Algae-Derived Biochar and Biopolymers: Synthesis, Preparation, and Potential Applications," Energies, MDPI, vol. 16(2), pages 1-23, January.
    7. Celiktas, Melih Soner & Alptekin, Fikret Muge, 2019. "Conversion of model biomass to carbon-based material with high conductivity by using carbonization," Energy, Elsevier, vol. 188(C).
    8. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    9. Li, Jian & Tao, Junyu & Yan, Beibei & Cheng, Kexin & Chen, Guanyi & Hu, Jianli, 2020. "Microwave reforming with char-supported Nickel-Cerium catalysts: A potential approach for thorough conversion of biomass tar model compound," Applied Energy, Elsevier, vol. 261(C).
    10. Taufer, Noah Luciano & Benedetti, Vittoria & Pecchi, Matteo & Matsumura, Yukihiko & Baratieri, Marco, 2021. "Coupling hydrothermal carbonization of digestate and supercritical water gasification of liquid products," Renewable Energy, Elsevier, vol. 173(C), pages 934-941.
    11. Bo Wang & Jie Yu & Hui Liao & Wenkun Zhu & Pingping Ding & Jian Zhou, 2020. "Adsorption of Lead (II) from Aqueous Solution with High Efficiency by Hydrothermal Biochar Derived from Honey," IJERPH, MDPI, vol. 17(10), pages 1-13, May.
    12. Yan, Mi & Liu, Yu & Song, Yucai & Xu, Aiming & Zhu, Gaojun & Jiang, Jiahao & Hantoko, Dwi, 2022. "Comprehensive experimental study on energy conversion of household kitchen waste via integrated hydrothermal carbonization and supercritical water gasification," Energy, Elsevier, vol. 242(C).
    13. Setter, C. & Oliveira, T.J.P., 2022. "Evaluation of the physical-mechanical and energy properties of coffee husk briquettes with kraft lignin during slow pyrolysis," Renewable Energy, Elsevier, vol. 189(C), pages 1007-1019.
    14. Umut Şen & Bruno Esteves & Helena Pereira, 2023. "Pyrolysis and Extraction of Bark in a Biorefineries Context: A Critical Review," Energies, MDPI, vol. 16(13), pages 1-23, June.
    15. Zhang, Yongsheng & Zahid, Ibrar & Danial, Ali & Minaret, Jamie & Cao, Yijun & Dutta, Animesh, 2021. "Hydrothermal carbonization of miscanthus: Processing, properties, and synergistic Co-combustion with lignite," Energy, Elsevier, vol. 225(C).
    16. Baena-Moreno, Francisco M. & Gonzalez-Castaño, Miriam & Arellano-García, Harvey & Reina, T.R., 2021. "Exploring profitability of bioeconomy paths: Dimethyl ether from biogas as case study," Energy, Elsevier, vol. 225(C).
    17. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    18. Qiu, L. & Deng, Y.F. & Wang, F. & Davaritouchaee, M. & Yao, Y.Q., 2019. "A review on biochar-mediated anaerobic digestion with enhanced methane recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    19. Ondrasek, G. & Bubalo Kovačić, M. & Carević, I. & Štirmer, N. & Stipičević, S. & Udiković-Kolić, N. & Filipović, V. & Romić, D. & Rengel, Z., 2021. "Bioashes and their potential for reuse to sustain ecosystem services and underpin circular economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    20. Yuchiao Lu & Hanmin Yang & Andrey V. Karasev & Chuan Wang & Pär G. Jönsson, 2022. "Applications of Hydrochar and Charcoal in the Iron and Steelmaking Industry—Part 1: Characterization of Carbonaceous Materials," Sustainability, MDPI, vol. 14(15), pages 1-27, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:2:p:1245-:d:1030105. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.