IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i13p10144-d1179888.html

CO 2 Adsorption Properties of Amine-Modified Zeolites Synthesized Using Different Types of Solid Waste

Author

Listed:
  • Shaojie Li

    (School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30# Xueyuan Road, Haidian District, Beijing 100083, China)

  • Shilong Jia

    (School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30# Xueyuan Road, Haidian District, Beijing 100083, China)

  • Tetsuya Nagasaka

    (Department of Metallurgy, Graduate School of Engineering, Tohoku University, 02 Aoba-yama, Sendai 980-8579, Japan)

  • Hao Bai

    (School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30# Xueyuan Road, Haidian District, Beijing 100083, China)

  • Liyun Yang

    (School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30# Xueyuan Road, Haidian District, Beijing 100083, China
    Department of Metallurgy, Graduate School of Engineering, Tohoku University, 02 Aoba-yama, Sendai 980-8579, Japan)

Abstract

In this study, organic amines were used to modify zeolite NaA and analcime synthesized using fly ash and iron tailing slag as raw materials, respectively, and the adsorption properties of the modified zeolites toward CO 2 were determined. We found that when tetraethylenepentamine (TEPA) was used, the modified zeolite NaA and analcime had the highest nitrogen content. The adsorption capacity of the modified zeolite NaA for CO 2 was 4.02 mmol/g and that of the modified analcime was 1.16 mmol/g when the adsorption temperature was 70 °C and the CO 2 flow rate was 50 mL/min. According to the adsorption isotherm, kinetic, and thermodynamic model fitting, the adsorption surface of the modified zeolite was not uniform, and the CO 2 adsorption of the modified zeolites was classified as chemical adsorption. In a mixed atmosphere of 15% CO 2 /85% N 2 , the dynamic selection coefficients of the modified zeolite NaA and analcime for CO 2 were 3.8942 and 2.9509, respectively; thus, the two amine-modified zeolites had good selectivity for CO 2 . After five cycles, the adsorption efficiencies of the modified zeolite NaA and modified analcime for CO 2 were 92.8% and 89%, respectively. Therefore, the two amine-modified zeolites showed good recycling performance.

Suggested Citation

  • Shaojie Li & Shilong Jia & Tetsuya Nagasaka & Hao Bai & Liyun Yang, 2023. "CO 2 Adsorption Properties of Amine-Modified Zeolites Synthesized Using Different Types of Solid Waste," Sustainability, MDPI, vol. 15(13), pages 1-18, June.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:13:p:10144-:d:1179888
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/13/10144/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/15/13/10144/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hedin, Niklas & Andersson, Linnéa & Bergström, Lennart & Yan, Jinyue, 2013. "Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption," Applied Energy, Elsevier, vol. 104(C), pages 418-433.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Joanna Siemak & Beata Michalkiewicz, 2023. "Adsorption Equilibrium of CO 2 on Microporous Activated Carbon Produced from Avocado Stone Using H 2 SO 4 as an Activating Agent," Sustainability, MDPI, vol. 15(24), pages 1-28, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Minkai & Guo, Yincheng, 2013. "Rate based modeling of absorption and regeneration for CO2 capture by aqueous ammonia solution," Applied Energy, Elsevier, vol. 111(C), pages 142-152.
    2. Prabu, V., 2015. "Integration of in-situ CO2-oxy coal gasification with advanced power generating systems performing in a chemical looping approach of clean combustion," Applied Energy, Elsevier, vol. 140(C), pages 1-13.
    3. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    4. Choi, Munkyoung & Cho, Minki & Lee, J.W., 2016. "Empirical formula for the mass flux in chemical absorption of CO2 with ammonia droplets," Applied Energy, Elsevier, vol. 164(C), pages 1-9.
    5. Wei, Ning & Li, Xiaochun & Wang, Yan & Zhu, Qianlin & Liu, Shengnan & Liu, Naizhong & Su, Xuebing, 2015. "Geochemical impact of aquifer storage for impure CO2 containing O2 and N2: Tongliao field experiment," Applied Energy, Elsevier, vol. 145(C), pages 198-210.
    6. Wang, Weilong & Li, Jiang & Wei, Xiaolan & Ding, Jing & Feng, Haijun & Yan, Jinyue & Yang, Jianping, 2015. "Carbon dioxide adsorption thermodynamics and mechanisms on MCM-41 supported polyethylenimine prepared by wet impregnation method," Applied Energy, Elsevier, vol. 142(C), pages 221-228.
    7. Alexander García-Mariaca & Eva Llera-Sastresa, 2021. "Review on Carbon Capture in ICE Driven Transport," Energies, MDPI, vol. 14(21), pages 1-30, October.
    8. Zhu, Xuancan & Shi, Yixiang & Cai, Ningsheng, 2016. "Integrated gasification combined cycle with carbon dioxide capture by elevated temperature pressure swing adsorption," Applied Energy, Elsevier, vol. 176(C), pages 196-208.
    9. Li, Shuangjun & Yuan, Xiangzhou & Deng, Shuai & Zhao, Li & Lee, Ki Bong, 2021. "A review on biomass-derived CO2 adsorption capture: Adsorbent, adsorber, adsorption, and advice," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    10. van der Spek, Mijndert & Ramirez, Andrea & Faaij, André, 2017. "Challenges and uncertainties of ex ante techno-economic analysis of low TRL CO2 capture technology: Lessons from a case study of an NGCC with exhaust gas recycle and electric swing adsorption," Applied Energy, Elsevier, vol. 208(C), pages 920-934.
    11. Bartela, Łukasz & Skorek-Osikowska, Anna & Kotowicz, Janusz, 2015. "An analysis of the investment risk related to the integration of a supercritical coal-fired combined heat and power plant with an absorption installation for CO2 separation," Applied Energy, Elsevier, vol. 156(C), pages 423-435.
    12. Kong, Yong & Shen, Xiaodong & Cui, Sheng & Fan, Maohong, 2015. "Development of monolithic adsorbent via polymeric sol–gel process for low-concentration CO2 capture," Applied Energy, Elsevier, vol. 147(C), pages 308-317.
    13. Liu, Xuetao & Saren, Sagar & Chen, Haonan & Jeong, Ji Hwan & Li, Minxia & Dang, Chaobin & Miyazaki, Takahiko & Thu, Kyaw, 2024. "Open adsorption system for atmospheric CO2 capture: Scaling and sensitivity analysis," Energy, Elsevier, vol. 294(C).
    14. Luis Míguez, José & Porteiro, Jacobo & Pérez-Orozco, Raquel & Patiño, David & Rodríguez, Sandra, 2018. "Evolution of CO2 capture technology between 2007 and 2017 through the study of patent activity," Applied Energy, Elsevier, vol. 211(C), pages 1282-1296.
    15. Qiu, Ziyang & Du, Tao & Yue, Qiang & Na, Hongming & Sun, Jingchao & Yuan, Yuxing & Che, Zichang & Wang, Yisong & Li, Yingnan, 2023. "A multi-parameters evaluation on exergy for hydrogen metallurgy," Energy, Elsevier, vol. 281(C).
    16. Su, Fengsheng & Lu, Chungsying & Chung, Ai-Ju & Liao, Chien-Hsiang, 2014. "CO2 capture with amine-loaded carbon nanotubes via a dual-column temperature/vacuum swing adsorption," Applied Energy, Elsevier, vol. 113(C), pages 706-712.
    17. Zhang, Wenbin & Liu, Hao & Sun, Yuan & Cakstins, Janis & Sun, Chenggong & Snape, Colin E., 2016. "Parametric study on the regeneration heat requirement of an amine-based solid adsorbent process for post-combustion carbon capture," Applied Energy, Elsevier, vol. 168(C), pages 394-405.
    18. Zima, Wiesław & Pawłowski, Adam & Grądziel, Sławomir & Cebula, Artur & Piwowarczyk, Monika & Kozak-Jagieła, Ewa & Majdak, Marek & Mondino, Giorgia & Skjervold, Vidar T., 2025. "CO2 capture from flue gases in a temperature swing moving bed – simulation results vs. the experiment," Energy, Elsevier, vol. 327(C).
    19. Kotowicz, Janusz & Brzęczek, Mateusz & Job, Marcin, 2018. "The thermodynamic and economic characteristics of the modern combined cycle power plant with gas turbine steam cooling," Energy, Elsevier, vol. 164(C), pages 359-376.
    20. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2015. "CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents," Applied Energy, Elsevier, vol. 140(C), pages 297-303.

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:13:p:10144-:d:1179888. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.