A Multi-Dimensional Investigation on Water Quality of Urban Rivers with Emphasis on Implications for the Optimization of Monitoring Strategy

Water quality monitoring (WQM) of urban rivers has been a reliable method to supervise the urban water environment. Indiscriminate WQM strategies can hardly emphasize the concerning pollution and usually require high costs of money, time, and manpower. To tackle these issues, this work carried out a multi-dimensional study (large spatial scale, multiple monitoring parameters, and long time scale) on the water quality of two urban rivers in Jiujiang City, China, which can provide indicative information for the optimization of WQM. Of note, the spatial distribution of NH 3 -N concentration varied significantly both in terms of the two different rivers as well as the different sections (i.e., much higher in the northern section), with a maximal difference, on average greater, than five times. Statistical methods and machine learning algorithms were applied to optimize the monitoring objects, parameters, and frequency. The sharp decrease in water quality of adjacent sections was identified by Analytical Hierarchy Process of water quality assessment indexes. After correlation analysis, principal component analysis, and cluster analysis, the various WQM parameters could be divided into three principal components and four clusters. With the machine learning algorithm of Random Forest, the relation between concentration of pollutants and rainfall depth was fitted using quadratic functions (calculated Pearson correlation coefficients ≥ 0.89), which could help predict the pollution after precipitation and further determine the appropriate WQM frequency. Generally, this work provides a novel thought for efficient, smart, and low-cost water quality investigation and monitoring strategy determination, which contributes to the construction of smart water systems and sustainable water source management.