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Enzymatic In Situ Interesterification of Rapeseed Oil with Methyl Formate in Diesel Fuel Medium

Author

Listed:
  • Violeta Makareviciene

    (Department of Environment and Ecology, Agricultural Academy, Vytautas Magnus University, K. Donelaicio Str. 58, LT-44248 Kaunas, Lithuania)

  • Kiril Kazancev

    (Department of Environment and Ecology, Agricultural Academy, Vytautas Magnus University, K. Donelaicio Str. 58, LT-44248 Kaunas, Lithuania)

  • Egle Sendzikiene

    (Department of Environment and Ecology, Agricultural Academy, Vytautas Magnus University, K. Donelaicio Str. 58, LT-44248 Kaunas, Lithuania)

  • Milda Gumbyte

    (Department of Environment and Ecology, Agricultural Academy, Vytautas Magnus University, K. Donelaicio Str. 58, LT-44248 Kaunas, Lithuania)

Abstract

The purpose of this research was to evaluate the process of enzymatic biodiesel synthesis by directly using rapeseed as a raw material, extracting the oil contained within and interesterifying with a mixture of methyl formate and mineral diesel, choosing the amount of mineral diesel so that the ratio between it and the rapeseed oil in the seeds was 9:1. As the final product of the interesterification process, a mixture of mineral diesel and biodiesel was obtained directly, which is conventionally produced by mixing the mineral diesel and biodiesel. The tests were performed using enzymatic catalysis using the lipase Lipozyme TL TIM. Process optimization was performed using the response surface methodology. A model describing the interaction of three independent variables and their influence on the yield of rapeseed oil methyl esters was developed. The physical and chemical indicators of the product obtained under optimal interesterification conditions were evaluated.

Suggested Citation

  • Violeta Makareviciene & Kiril Kazancev & Egle Sendzikiene & Milda Gumbyte, 2024. "Enzymatic In Situ Interesterification of Rapeseed Oil with Methyl Formate in Diesel Fuel Medium," Energies, MDPI, vol. 17(2), pages 1-13, January.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:2:p:282-:d:1313886
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    References listed on IDEAS

    as
    1. Migle Santaraite & Egle Sendzikiene & Violeta Makareviciene & Kiril Kazancev, 2020. "Biodiesel Production by Lipase-Catalyzed in Situ Transesterification of Rapeseed Oil Containing a High Free Fatty Acid Content with Ethanol in Diesel Fuel Media," Energies, MDPI, vol. 13(10), pages 1-12, May.
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