IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v178y2021icp202-211.html
   My bibliography  Save this article

Non-fullerene organic photovoltaics based on thienopyrroledione comprising random copolymers; effect of alkyl chains

Author

Listed:
  • Yasa, Mustafa
  • Depci, Tolga
  • Alemdar, Eda
  • Hacioglu, Serife O.
  • Cirpan, Ali
  • Toppare, Levent

Abstract

Two new random donor-acceptor (D-A) copolymers, signed as P1 and P2, were designed and synthesized. Electrochemical and spectroelectrochemical measurements were performed to investigate absorption, energy levels, electronic and optical band gaps for comparison. The polymers were used as donor polymers in the active layer to fabricate non-fullerene, bulk heterojunction (BHJ) organic photovoltaics (OPVs). Investigations were carried out through the conventional BHJ structure; ITO/PEDOT: PSS/Active Layer/LiF/Al, where active layer consists of 3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2′,3′-d’]-s-indaceno[1,2-b:5,6-b’]dithiophene (ITIC) as the acceptor and thienopyrroledione containing donors. The device based on P1:ITIC(1:1) blend with a thickness of 161 nm gave the best performance with a power conversion efficiency (PCE) of 7.94%, an open-circuit voltage (VOC) of 0.86 V, a short-current density (JSC) of 18.45 mA cm−2 and a fill factor (FF) of 50.12%. The highest PCE obtained from P2 based organic solar cell is 1.96%. P2 exhibited low solubility attributed to the lack of alkyl groups enhancing polymer solubility, electronic properties, and photovoltaic performances. The research outputs exhibit that introduction of alkyl chains on the polymer backbone can enhance device performance.

Suggested Citation

  • Yasa, Mustafa & Depci, Tolga & Alemdar, Eda & Hacioglu, Serife O. & Cirpan, Ali & Toppare, Levent, 2021. "Non-fullerene organic photovoltaics based on thienopyrroledione comprising random copolymers; effect of alkyl chains," Renewable Energy, Elsevier, vol. 178(C), pages 202-211.
    • Handle: RePEc:eee:renene:v:178:y:2021:i:c:p:202-211
    DOI: 10.1016/j.renene.2021.06.087
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121009538
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.06.087?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Roy, Debmalya & Shastri, Babita & Imamuddin, Md. & Mukhopadhyay, K. & Rao, K.U. Bhasker, 2011. "Nanostructured carbon and polymer materials – Synthesis and their application in energy conversion devices," Renewable Energy, Elsevier, vol. 36(3), pages 1014-1018.
    2. Wu, Wenjun & Li, Jing & Guo, Fuling & Zhang, Lei & Long, Yitao & Hua, Jianli, 2010. "Photovoltaic performance and long-term stability of quasi-solid-state fluoranthene dyes-sensitized solar cells," Renewable Energy, Elsevier, vol. 35(8), pages 1724-1728.
    3. Keles, Duygu & Erer, Mert Can & Bolayir, Eda & Cevher, Sevki Can & Hizalan, Gonul & Toppare, Levent & Cirpan, Ali, 2019. "Conjugated polymers with benzothiadiazole and benzotriazole moieties for polymer solar cells," Renewable Energy, Elsevier, vol. 139(C), pages 1184-1193.
    4. Hu, Ziyang & Zhang, Jianjun & Huang, Like & Sun, Jingyang & Zhang, Ting & He, Hongyun & Zhang, Jing & Zhang, Houcheng & Zhu, Yuejin, 2015. "Natural drying effect on active layer for achieving high performance in polymer solar cells," Renewable Energy, Elsevier, vol. 74(C), pages 11-17.
    5. Jacobus J. van Franeker & Mathieu Turbiez & Weiwei Li & Martijn M Wienk & René A.J. Janssen, 2015. "A real-time study of the benefits of co-solvents in polymer solar cell processing," Nature Communications, Nature, vol. 6(1), pages 1-8, May.
    6. (Celik) Bedeloglu, Ayse & Demir, Ali & Bozkurt, Yalcin & Sariciftci, Niyazi Serdar, 2010. "Photovoltaic properties of polymer based organic solar cells adapted for non-transparent substrates," Renewable Energy, Elsevier, vol. 35(10), pages 2301-2306.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dehaudt, Jérémy & Husson, Jérôme & Guyard, Laurent & Oswald, Frédéric & Martineau, David, 2014. "A simple access to “Black-Dye” analogs with good efficiencies in dye-sensitized solar cells," Renewable Energy, Elsevier, vol. 66(C), pages 588-595.
    2. Guai, Guan Hong & Song, Qun Liang & Lu, Zhi Song & Ng, Chee Mang & Li, Chang Ming, 2013. "Tailor and functionalize TiO2 compact layer by acid treatment for high performance dye-sensitized solar cell and its enhancement mechanism," Renewable Energy, Elsevier, vol. 51(C), pages 29-35.
    3. Liang, Mao & Wang, Zhong-Yuan & Zhang, Lu & Han, Hong-Yu & Sun, Zhe & Xue, Song, 2011. "New organic photosensitizers incorporating carbazole and dimethylarylamine moieties for dye-sensitized solar cells," Renewable Energy, Elsevier, vol. 36(10), pages 2711-2716.
    4. Maçaira, José & Andrade, Luísa & Mendes, Adélio, 2013. "Review on nanostructured photoelectrodes for next generation dye-sensitized solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 334-349.
    5. Freitas, Alessandro M. & Gomes, Rodrigo A.M. & Ferreira, Rafael A.M. & Porto, Matheus P., 2019. "Experimental performance of commercial OPV panels tested outdoor," Renewable Energy, Elsevier, vol. 135(C), pages 1004-1012.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:178:y:2021:i:c:p:202-211. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.