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Investigation on catalytic hydrodeoxygenation of eugenol blend with light fraction in bio-oil over Ni-based catalysts

Author

Listed:
  • Chen, Guanyi
  • Liu, Juping
  • Li, Xiangping
  • Zhang, Jianguang
  • Yin, Han
  • Su, Zhenping

Abstract

In this work, HZSM-5, Al-SBA-15 and Al-SBA-15/HZSM-5 were adopted as supporting materials for the nickel-based catalysts used in hydrodeoxygenation process. Incipient wetness impregnation method was employed to load nickel species onto these materials. The physicochemical characterization was carried out using advanced instruments. The effect of composition of nickel-based catalysts on hydrodeoxygenation (HDO) reaction was studied. Support materials of nickel-based catalyst have a significantly impact on HDO activity. The highest selectivity (67.9%) of propyl-cyclohexane was obtained over nickel based Al-SBA-15/HZSM-5 catalyst, and nearly all the eugenol was completely hydrodeoxygenated after reaction. The impact of light fractions existed in bio-oil on phenols upgrading process was investigated. The conversion of eugenol mixed with light fractions reached nearly 100% for all the reactions. Eugenol mixed with light fractions as reactant could reduce ring break reaction during hydrodeoxygenation process. The selectivity of alkanes remained nearly unchanged after adding ethylene glycol into the reactant. However, the selectivity of propyl-cyclohexane was significantly decreased by mixing furfural or acetic acid with eugenol as reactant.

Suggested Citation

  • Chen, Guanyi & Liu, Juping & Li, Xiangping & Zhang, Jianguang & Yin, Han & Su, Zhenping, 2020. "Investigation on catalytic hydrodeoxygenation of eugenol blend with light fraction in bio-oil over Ni-based catalysts," Renewable Energy, Elsevier, vol. 157(C), pages 456-465.
    • Handle: RePEc:eee:renene:v:157:y:2020:i:c:p:456-465
    DOI: 10.1016/j.renene.2020.05.040
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    References listed on IDEAS

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    1. Li, Xiangping & Chen, Lei & Chen, Guanyi & Zhang, Jianguang & Liu, Juping, 2020. "The relationship between acidity, dispersion of nickel, and performance of Ni/Al-SBA-15 catalyst on eugenol hydrodeoxygenation," Renewable Energy, Elsevier, vol. 149(C), pages 609-616.
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    Cited by:

    1. Chaihad, Nichaboon & Situmorang, Yohanes Andre & Anniwaer, Aisikaer & Kurnia, Irwan & Karnjanakom, Surachai & Kasai, Yutaka & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2021. "Preparation of various hierarchical HZSM-5 based catalysts for in-situ fast upgrading of bio-oil," Renewable Energy, Elsevier, vol. 169(C), pages 283-292.
    2. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.
    3. Shu, Riyang & Jiang, Hao & Xie, Long & Liu, Xiaozhou & Yin, Tao & Tian, Zhipeng & Wang, Chao & Chen, Ying, 2023. "Efficient hydrodeoxygenation of lignin-derived phenolic compounds by using Ru-based biochar catalyst coupled with silicotungstic acid," Renewable Energy, Elsevier, vol. 202(C), pages 1160-1168.
    4. Li, Sen & Guo, Longhui & He, Xinyu & Qiao, Congzhen & Tian, Yajie, 2022. "Synthesis of uniform Ni nanoparticles encapsulated in ZSM–5 for selective hydrodeoxygenation of phenolics," Renewable Energy, Elsevier, vol. 194(C), pages 89-99.

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