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An experimental investigation into the use of molten carbonate fuel cells to capture CO2 from gas turbine exhaust gases

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  • Amorelli, A
  • Wilkinson, M.B
  • Bedont, P
  • Capobianco, P
  • Marcenaro, B
  • Parodi, F
  • Torazza, A

Abstract

As part of its climate change mitigation initiative, BP is evaluating technologies for the separation and capture of CO2 from combustion sources, for subsequent geologic storage. Ansaldo Fuel Cells S.p.A. is developing molten carbonate fuel cell (MCFC) technology targeted at industrial applications from 50 kW to 10 MW. This paper describes the conceptual design of a hybrid MCFC system to generate power and simultaneously capture CO2 from small (<10 MW) gas turbine exhaust streams. Initial modeling studies indicated that a 1.6 MW MCFC could reduce the CO2 emissions from a 4.6 MW gas turbine by 50% on a per kWh basis. Experimental studies are in progress to understand the system behaviour, operating envelope and impact of contaminants. Initial data from these investigations are presented, which confirm that the fuel cell can operate at sub-optimal CO2 levels with limited loss in power and efficiency.

Suggested Citation

  • Amorelli, A & Wilkinson, M.B & Bedont, P & Capobianco, P & Marcenaro, B & Parodi, F & Torazza, A, 2004. "An experimental investigation into the use of molten carbonate fuel cells to capture CO2 from gas turbine exhaust gases," Energy, Elsevier, vol. 29(9), pages 1279-1284.
    • Handle: RePEc:eee:energy:v:29:y:2004:i:9:p:1279-1284
    DOI: 10.1016/j.energy.2004.03.087
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    Cited by:

    1. Wang, Fu & Deng, Shuai & Zhang, Houcheng & Wang, Jiatang & Zhao, Jiapei & Miao, He & Yuan, Jinliang & Yan, Jinyue, 2020. "A comprehensive review on high-temperature fuel cells with carbon capture," Applied Energy, Elsevier, vol. 275(C).
    2. Wee, Jung-Ho, 2011. "Molten carbonate fuel cell and gas turbine hybrid systems as distributed energy resources," Applied Energy, Elsevier, vol. 88(12), pages 4252-4263.
    3. Campanari, Stefano & Manzolini, Giampaolo & Chiesa, Paolo, 2013. "Using MCFC for high efficiency CO2 capture from natural gas combined cycles: Comparison of internal and external reforming," Applied Energy, Elsevier, vol. 112(C), pages 772-783.
    4. Duan, Liqiang & Xia, Kun & Feng, Tao & Jia, Shilun & Bian, Jing, 2016. "Study on coal-fired power plant with CO2 capture by integrating molten carbonate fuel cell system," Energy, Elsevier, vol. 117(P2), pages 578-589.
    5. Kalina, Jacek, 2016. "Complex thermal energy conversion systems for efficient use of locally available biomass," Energy, Elsevier, vol. 110(C), pages 105-115.
    6. Kuramochi, Takeshi & Ramírez, Andrea & Turkenburg, Wim & Faaij, André, 2013. "Techno-economic prospects for CO2 capture from distributed energy systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 19(C), pages 328-347.
    7. Wee, Jung-Ho, 2010. "Contribution of fuel cell systems to CO2 emission reduction in their application fields," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 735-744, February.
    8. Barckholtz, Timothy A. & Taylor, Kevin M. & Narayanan, Sundar & Jolly, Stephen & Ghezel-Ayagh, Hossein, 2022. "Molten carbonate fuel cells for simultaneous CO2 capture, power generation, and H2 generation," Applied Energy, Elsevier, vol. 313(C).
    9. Campanari, S. & Chiesa, P. & Manzolini, G. & Bedogni, S., 2014. "Economic analysis of CO2 capture from natural gas combined cycles using Molten Carbonate Fuel Cells," Applied Energy, Elsevier, vol. 130(C), pages 562-573.
    10. Duan, Liqiang & Zhu, Jingnan & Yue, Long & Yang, Yongping, 2014. "Study on a gas-steam combined cycle system with CO2 capture by integrating molten carbonate fuel cell," Energy, Elsevier, vol. 74(C), pages 417-427.
    11. Wee, Jung-Ho, 2014. "Carbon dioxide emission reduction using molten carbonate fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 178-191.
    12. Grasham, Oliver & Dupont, Valerie & Camargo-Valero, Miller Alonso & García-Gutiérrez, Pelayo & Cockerill, Timothy, 2019. "Combined ammonia recovery and solid oxide fuel cell use at wastewater treatment plants for energy and greenhouse gas emission improvements," Applied Energy, Elsevier, vol. 240(C), pages 698-708.

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