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Black liquor gasification—consequences for both industry and society

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  • Eriksson, H.
  • Harvey, S.

Abstract

The pulp and paper industry consumes large quantities of biofuels to satisfy process requirements. Biomass is however a limited resource, to be used as effectively as possible. Modern pulping operations have excess internal fuels compared to the amounts needed to satisfy process steam demands. The excess fuel is often used for cogeneration of electric power. If market biofuel availability at a reasonable price is limited, import/export to/from a mill however changes the amount of such biofuel available for alternative users. This work compares different mill powerhouse technologies and CHP plant configurations (including conventional recovery boiler technology and black liquor gasification technology) with respect to electric power output from a given fuel resource. Different process steam demand levels for different representative mill types are considered. The comparison accounts for decreased/increased electricity production in an alternative energy system when biofuel is imported/exported to/from the mill. The results show that black liquor gasification is in all cases considered an attractive powerhouse recovery cycle technology. For moderate values of the marginal electric power generation efficiency for biofuel exported to the reference alternative energy system, excess mill internal biofuel should be used on mill site for gas turbine based CHP power generation. The remaining excess biofuels in market pulp mills should be exported and used in the reference alternative energy system in this case. For integrated pulp and paper mills, biofuel should be imported, but only for cogeneration usage (i.e. condensing power units should be avoided). If biofuel can be used elsewhere for high efficiency CHP power generation, mill internal biofuel should be used exclusively for process heating, and the remainder should be exported.

Suggested Citation

  • Eriksson, H. & Harvey, S., 2004. "Black liquor gasification—consequences for both industry and society," Energy, Elsevier, vol. 29(4), pages 581-612.
  • Handle: RePEc:eee:energy:v:29:y:2004:i:4:p:581-612
    DOI: 10.1016/j.energy.2003.09.005
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    Cited by:

    1. Guangzai Nong & Zongwen Zhou & Shuangfei Wang, 2015. "Generation of Hydrogen, Lignin and Sodium Hydroxide from Pulping Black Liquor by Electrolysis," Energies, MDPI, vol. 9(1), pages 1-11, December.
    2. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Bio-refinery system in a pulp mill for methanol production with comparison of pressurized black liquor gasification and dry gasification using direct causticization," Applied Energy, Elsevier, vol. 90(1), pages 24-31.
    3. Darmawan, Arif & Hardi, Flabianus & Yoshikawa, Kunio & Aziz, Muhammad & Tokimatsu, Koji, 2017. "Enhanced process integration of black liquor evaporation, gasification, and combined cycle," Applied Energy, Elsevier, vol. 204(C), pages 1035-1042.
    4. Joelsson, Jonas M. & Gustavsson, Leif, 2012. "Reductions in greenhouse gas emissions and oil use by DME (di-methyl ether) and FT (Fischer-Tropsch) diesel production in chemical pulp mills," Energy, Elsevier, vol. 39(1), pages 363-374.
    5. Cao, Changqing & Guo, Liejin & Jin, Hui & Cao, Wen & Jia, Yi & Yao, Xiangdong, 2017. "System analysis of pulping process coupled with supercritical water gasification of black liquor for combined hydrogen, heat and power production," Energy, Elsevier, vol. 132(C), pages 238-247.
    6. Pettersson, Karin & Harvey, Simon, 2010. "CO2 emission balances for different black liquor gasification biorefinery concepts for production of electricity or second-generation liquid biofuels," Energy, Elsevier, vol. 35(2), pages 1101-1106.
    7. Laurijssen, Jobien & Faaij, André & Worrell, Ernst, 2012. "Energy conversion strategies in the European paper industry – A case study in three countries," Applied Energy, Elsevier, vol. 98(C), pages 102-113.
    8. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
    9. Nong, Guangzai & Huang, Lijie & Mo, Haitao & Wang, Shuangfei, 2013. "Investigate the variability of gas compositions and thermal efficiency of bagasse black liquor gasification," Energy, Elsevier, vol. 49(C), pages 178-181.
    10. Andersson, E. & Harvey, S., 2007. "Comparison of pulp-mill-integrated hydrogen production from gasified black liquor with stand-alone production from gasified biomass," Energy, Elsevier, vol. 32(4), pages 399-405.
    11. Pettersson, Karin & Harvey, Simon, 2012. "Comparison of black liquor gasification with other pulping biorefinery concepts – Systems analysis of economic performance and CO2 emissions," Energy, Elsevier, vol. 37(1), pages 136-153.

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