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Multi-electron reactions for the synthesis of a vanadium-based amorphous material as lithium-ion battery cathode with high specific capacity

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  • Kong, Fanhou
  • Liang, Xue
  • Yi, Lanlin
  • Fang, Xiaohui
  • Yin, Zhongbin
  • Wang, Yulong
  • Zhang, Ruixiang
  • Liu, Longyang
  • Chen, Qing
  • Li, Minghan
  • Li, Changjiu
  • Jiang, Hong
  • Chen, Yongjun

Abstract

The vanadium-based amorphous electrode material can realize the valence state conversion and increase its specific capacity through the multi-electron reaction. We have obtained V2O5–Li3PO4 glass with a strong reducing agent CaC2, realizing a multi-electron reaction of V5+ to V4+ and then to V3+ in the model system. Moreover, we have explored the relationship between valence state, crystallinity, and conductivity limit to compare the cycle performances of amorphous glass batteries. The CaC2 content of 20%, V4+ presented the dominating valence state with a content of 77.5%. VP-C20% exhibited a maximum specific capacity of 319.3 mAh g−1, and the specific capacity after 100 cycles was 280.3 mAh g−1, corresponding to a retention capacity of 87.8%. The electrochemical performance of amorphous vanadium oxide decreased with the increase of the LiV2O5’s nanocrystallinity. Crystallinity and the controllable multi-electron reaction could provide an important reference for designing other new electrode materials with high capacity and long cycle life.

Suggested Citation

  • Kong, Fanhou & Liang, Xue & Yi, Lanlin & Fang, Xiaohui & Yin, Zhongbin & Wang, Yulong & Zhang, Ruixiang & Liu, Longyang & Chen, Qing & Li, Minghan & Li, Changjiu & Jiang, Hong & Chen, Yongjun, 2021. "Multi-electron reactions for the synthesis of a vanadium-based amorphous material as lithium-ion battery cathode with high specific capacity," Energy, Elsevier, vol. 219(C).
    • Handle: RePEc:eee:energy:v:219:y:2021:i:c:s0360544220326207
    DOI: 10.1016/j.energy.2020.119513
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    References listed on IDEAS

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    2. Wu, Yaqin & Wang, Feiyue & Fan, Zhupu & Wang, Zihang & Yang, Wenying & Ju, Wenqin & Lei, Weixin & Zou, Youlan & Ma, Zengsheng, 2022. "Internally enhanced conductive 3D porous hierarchical biochar framework for lithium sulfur battery," Energy, Elsevier, vol. 255(C).

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