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Improving fuel quality by whole crude oil hydrotreating: A kinetic model for hydrodeasphaltenization in a trickle bed reactor

Author

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  • Jarullah, A.T.
  • Mujtaba, I.M.
  • Wood, A.S.

Abstract

Fossil fuel is still a predominant source of the global energy requirement. Hydrotreating of whole crude oil has the ability to increase the productivity of middle distillate fractions and improve the fuel quality by simultaneously reducing contaminants such as sulfur, nitrogen, vanadium, nickel and asphaltene to the levels required by the regulatory bodies. Hydrotreating is usually carried out in a trickle bed reactor (TBR) where hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodemetallization (HDM) and hydrodeasphaltenization (HDAs) reactions take place simultaneously. To develop a detailed and a validated TBR process model which can be used for design and optimization of the hydrotreating process, it is essential to develop kinetic models for each of these reactions. Most recently, the authors have developed kinetic models for all of these chemical reactions except that of HDAs. In this work, a kinetic model (in terms of kinetic parameters) for the HDAs reaction in the TBR is developed.

Suggested Citation

  • Jarullah, A.T. & Mujtaba, I.M. & Wood, A.S., 2012. "Improving fuel quality by whole crude oil hydrotreating: A kinetic model for hydrodeasphaltenization in a trickle bed reactor," Applied Energy, Elsevier, vol. 94(C), pages 182-191.
    • Handle: RePEc:eee:appene:v:94:y:2012:i:c:p:182-191
    DOI: 10.1016/j.apenergy.2012.01.044
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    Cited by:

    1. Zhang, Yuming & Yu, Deping & Li, Wangliang & Gao, Shiqiu & Xu, Guangwen & Zhou, Huaqun & Chen, Jing, 2013. "Fundamental study of cracking gasification process for comprehensive utilization of vacuum residue," Applied Energy, Elsevier, vol. 112(C), pages 1318-1325.
    2. Zhang, Qian & Li, Qingfeng & Zhang, Linxian & Wang, Zhiqing & Jing, Xuliang & Yu, Zhongliang & Song, Shuangshuang & Fang, Yitian, 2014. "Preliminary study on co-gasification behavior of deoiled asphalt with coal and biomass," Applied Energy, Elsevier, vol. 132(C), pages 426-434.
    3. Shastitko. Andrey (Шаститко, Андрей) & Komkova, Anastasia Andreevna (Комкова, Анастасия Андреевна) & Kurdin, Alexander (Курдин, Александр) & Shastitko, Anastasia (Шаститко, Анастасия), 2016. "Competition Policy and Incentives for Innovation [Конкурентная Политика И Стимулы К Инновационной Деятельности]," Working Papers 1447, Russian Presidential Academy of National Economy and Public Administration.
    4. Quan, Hongping & Li, Pengfei & Duan, Wenmeng & Chen, Liao & Xing, Langman, 2019. "A series of methods for investigating the effect of a flow improver on the asphaltene and resin of crude oil," Energy, Elsevier, vol. 187(C).
    5. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.

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