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Vanadium redox flow battery capacity loss mitigation strategy based on a comprehensive analysis of electrolyte imbalance effects

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  • Puleston, Thomas
  • Serra, Maria
  • Costa-Castelló, Ramon

Abstract

Electrolyte imbalance is the main cause of capacity loss in vanadium redox flow batteries. It has been widely reported that imbalance caused by vanadium crossover can be readily recovered by remixing the electrolytes, while imbalance caused by a net oxidation of the electrolyte can only be reverted by means of more complex chemical or electrochemical methods. At the moment, however, the joint effect of both types of imbalances on the battery capacity is still not well understood. To overcome this limitation, generalised State of Charge and State of Health indicators that consider both types of imbalances are derived in this work. Subsequently, a thorough analysis on how the battery capacity depends on electrolyte imbalance is performed. As a result of this analysis, two specific outcomes are highlighted. Firstly, it is shown that standard electrolyte remixing may be counterproductive under certain imbalance conditions, further reducing the battery capacity instead of augmenting it. Secondly, it is demonstrated that most of the capacity loss caused by oxidation can be mitigated by inducing an optimal mass imbalance in the system. Consequently, a systematic procedure to track this optimum is proposed and validated through computer simulation.

Suggested Citation

  • Puleston, Thomas & Serra, Maria & Costa-Castelló, Ramon, 2024. "Vanadium redox flow battery capacity loss mitigation strategy based on a comprehensive analysis of electrolyte imbalance effects," Applied Energy, Elsevier, vol. 355(C).
    • Handle: RePEc:eee:appene:v:355:y:2024:i:c:s0306261923016355
    DOI: 10.1016/j.apenergy.2023.122271
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    References listed on IDEAS

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    1. Pugach, M. & Kondratenko, M. & Briola, S. & Bischi, A., 2018. "Zero dimensional dynamic model of vanadium redox flow battery cell incorporating all modes of vanadium ions crossover," Applied Energy, Elsevier, vol. 226(C), pages 560-569.
    2. Frate, Guido Francesco & Ferrari, Lorenzo & Desideri, Umberto, 2021. "Energy storage for grid-scale applications: Technology review and economic feasibility analysis," Renewable Energy, Elsevier, vol. 163(C), pages 1754-1772.
    3. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    4. Kalvin Schofield & Petr Musilek, 2022. "State of Charge and Capacity Tracking in Vanadium Redox Flow Battery Systems," Clean Technol., MDPI, vol. 4(3), pages 1-12, June.
    5. Bhattarai, Arjun & Wai, Nyunt & Schweiss, Rüdiger & Whitehead, Adam & Scherer, Günther G. & Ghimire, Purna C. & Lim, Tuti M. & Hng, Huey Hoon, 2019. "Vanadium redox flow battery with slotted porous electrodes and automatic rebalancing demonstrated on a 1 kW system level," Applied Energy, Elsevier, vol. 236(C), pages 437-443.
    6. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
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