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Layered cobalt nickel silicate hollow spheres as a highly-stable supercapacitor material

Author

Listed:
  • Rong, Qing
  • Long, Lu-Lu
  • Zhang, Xing
  • Huang, Yu-Xi
  • Yu, Han-Qing

Abstract

Among the actively studied electrode materials, layered cobalt or nickel compounds have been recognized as a family of promising electrode materials for supercapacitor. However, the cycling performance of these materials is unsatisfactory by far. In this work, a novel and stable layered cobalt nickel silicate hollow sphere compound was prepared for supercapacitor application using a facile hydrothermal synthetic approach. The obtained material exhibited a good specific capacitance and outstanding long-term cycling stability (only 0.7% and 5% losses of its initial specific capacitance after 10,000 and 20,000 cycles, respectively) at a high current density of 20A/g after annealing at 600°C. This work provides new insights of designing novel cobalt or nickel compounds for supercapacitor with excellent stability, and promotes the application of layered metal silicates as advanced supercapacitor materials.

Suggested Citation

  • Rong, Qing & Long, Lu-Lu & Zhang, Xing & Huang, Yu-Xi & Yu, Han-Qing, 2015. "Layered cobalt nickel silicate hollow spheres as a highly-stable supercapacitor material," Applied Energy, Elsevier, vol. 153(C), pages 63-69.
  • Handle: RePEc:eee:appene:v:153:y:2015:i:c:p:63-69
    DOI: 10.1016/j.apenergy.2014.11.077
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    References listed on IDEAS

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    1. H. B. Li & M. H. Yu & F. X. Wang & P. Liu & Y. Liang & J. Xiao & C. X. Wang & Y. X. Tong & G. W. Yang, 2013. "Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials," Nature Communications, Nature, vol. 4(1), pages 1-7, October.
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    Cited by:

    1. Zhang, Jijun & Chen, Zexiang & Wang, Yan & Li, Hai, 2016. "Morphology-controllable synthesis of 3D CoNiO2 nano-networks as a high-performance positive electrode material for supercapacitors," Energy, Elsevier, vol. 113(C), pages 943-948.

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