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Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions

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  • Sanchez-Jimenez, P.E.
  • Perez-Maqueda, L.A.
  • Valverde, J.M.

Abstract

This work presents a CO2 sorbent that may be synthesized from low-cost and widely available materials following a simple method basically consisting of impregnation of a nanostructured silica support with a saturated solution of calcium nitrate. In a first impregnation stage, the use of a stoichiometric CaO/SiO2 ratio serves to produce a calcium silicate matrix after calcination. This calcium silicate matrix acts as a thermally stable and mechanically hard support for CaO deposited on it by further impregnation. The CaO-impregnated sorbent exhibits a stable CaO conversion at Ca-looping conditions whose value depends on the CaO wt% deposited on the calcium silicate matrix, which can be increased by successive reimpregnations. A 10wt% CaO impregnated sorbent reaches a stable conversion above 0.6 whereas the stable conversion of a 30wt% CaO impregnated sorbent is around 0.3, which is much larger than the residual conversion of CaO derived from natural limestone (between 0.07 and 0.08). Moreover, particle size distribution measurements of samples predispersed in a liquid and subjected to high energy ultrasonic waves indicate that the CaO-impregnated sorbent has a relatively high mechanical strength as compared to limestone derived CaO.

Suggested Citation

  • Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Valverde, J.M., 2014. "Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions," Applied Energy, Elsevier, vol. 118(C), pages 92-99.
    • Handle: RePEc:eee:appene:v:118:y:2014:i:c:p:92-99
    DOI: 10.1016/j.apenergy.2013.12.024
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    References listed on IDEAS

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    1. Valverde, Jose M. & Sanchez-Jimenez, Pedro E. & Perejon, Antonio & Perez-Maqueda, Luis A., 2013. "Constant rate thermal analysis for enhancing the long-term CO2 capture of CaO at Ca-looping conditions," Applied Energy, Elsevier, vol. 108(C), pages 108-120.
    2. Lisbona, Pilar & Martínez, Ana & Romeo, Luis M., 2013. "Hydrodynamical model and experimental results of a calcium looping cycle for CO2 capture," Applied Energy, Elsevier, vol. 101(C), pages 317-322.
    3. Chen, Shiyi & Xiang, Wenguo & Wang, Dong & Xue, Zhipeng, 2012. "Incorporating IGCC and CaO sorption-enhanced process for power generation with CO2 capture," Applied Energy, Elsevier, vol. 95(C), pages 285-294.
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    3. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    4. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    5. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2014. "Calcium-looping for post-combustion CO2 capture. On the adverse effect of sorbent regeneration under CO2," Applied Energy, Elsevier, vol. 126(C), pages 161-171.
    6. Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
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    9. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    10. Gong, Xuzhong & Zhang, Tong & Zhang, Junqiang & Wang, Zhi & Liu, Junhao & Cao, Jianwei & Wang, Chuan, 2022. "Recycling and utilization of calcium carbide slag - current status and new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    11. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    12. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    13. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Quintanilla, M.A.S. & Perez-Vaquero, J., 2014. "Role of crystal structure on CO2 capture by limestone derived CaO subjected to carbonation/recarbonation/calcination cycles at Ca-looping conditions," Applied Energy, Elsevier, vol. 125(C), pages 264-275.
    14. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    15. Wang, Wenjing & Li, Yingjie & Xie, Xin & Sun, Rongyue, 2014. "Effect of the presence of HCl on cyclic CO2 capture of calcium-based sorbent in calcium looping process," Applied Energy, Elsevier, vol. 125(C), pages 246-253.
    16. Xie, Xin & Li, Yingjie & Wang, Wenjing & Shi, Lei, 2014. "HCl removal using cycled carbide slag from calcium looping cycles," Applied Energy, Elsevier, vol. 135(C), pages 391-401.
    17. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    18. Hafizi, A. & Rahimpour, M.R. & Hassanajili, S., 2016. "High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent," Applied Energy, Elsevier, vol. 169(C), pages 629-641.
    19. Wang, Ke & Hu, Xiumeng & Zhao, Pengfei & Yin, Zeguang, 2016. "Natural dolomite modified with carbon coating for cyclic high-temperature CO2 capture," Applied Energy, Elsevier, vol. 165(C), pages 14-21.
    20. Zare Ghorbaei, S. & Ale Ebrahim, H., 2022. "Comparison of kinetics and thermochemical energy storage capacities of strontium oxide, calcium oxide, and magnesium oxide during carbonation reaction," Renewable Energy, Elsevier, vol. 184(C), pages 765-775.
    21. Tian, Sicong & Li, Kaimin & Jiang, Jianguo & Chen, Xuejing & Yan, Feng, 2016. "CO2 abatement from the iron and steel industry using a combined Ca–Fe chemical loop," Applied Energy, Elsevier, vol. 170(C), pages 345-352.
    22. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    23. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2015. "Ca-looping for postcombustion CO2 capture: A comparative analysis on the performances of dolomite and limestone," Applied Energy, Elsevier, vol. 138(C), pages 202-215.
    24. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    25. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.

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    Keywords

    CO2 capture; Ca-based synthetic sorbents; Ca-looping;
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