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Illustrating new understanding of adsorbed water on silica for inducing tetrahedral cobalt(II) for propane dehydrogenation

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  • Zijun Huang

    (Kunming University of Science and Technology
    Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province
    The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province)

  • Dedong He

    (Kunming University of Science and Technology
    Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province
    The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province)

  • Weihua Deng

    (Kunming University of Science and Technology
    Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province)

  • Guowu Jin

    (Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province
    The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province)

  • Ke Li

    (Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province
    The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province)

  • Yongming Luo

    (Kunming University of Science and Technology
    Kunming University of Science and Technology
    The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province
    The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province)

Abstract

Highly dispersed metal sites on the surface of silica, achieved from immobilization of metal precursor within hydroxyl groups, has gained increasing attention in the field of heterogeneous catalyst. However, the special role of adsorbed water derived by hydroxyl groups on the silica is generally ignored. Herein, a new understanding of adsorbed water on the formation of highly dispersed tetrahedral Co(II) (Td-cobalt(II)) sites is illustrated. It is indicated that sufficient adsorbed water induces the transformation of precursor of Co(NO3)2 into intermediate of [Co(H2O)6]2+. Subsequently, [Co(H2O)6]2+ makes the highly dispersed Td-cobalt(II) sites to be available during direct H2-reduction process. A systematic characterization and DFT calculation prove the existence of the adsorbed water and the importance of the intermediate of [Co(H2O)6]2+, respectively. The as-synthesized catalyst is attempted to the propane dehydrogenation, which shows better reactivity when compared with other reported Co based catalysts.

Suggested Citation

  • Zijun Huang & Dedong He & Weihua Deng & Guowu Jin & Ke Li & Yongming Luo, 2023. "Illustrating new understanding of adsorbed water on silica for inducing tetrahedral cobalt(II) for propane dehydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35698-0
    DOI: 10.1038/s41467-022-35698-0
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    References listed on IDEAS

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    1. Carlos Hernández Mejía & Tom W. Deelen & Krijn P. Jong, 2018. "Activity enhancement of cobalt catalysts by tuning metal-support interactions," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Nicole J. LiBretto & Yinan Xu & Aubrey Quigley & Ethan Edwards & Rhea Nargund & Juan Carlos Vega-Vila & Richard Caulkins & Arunima Saxena & Rajamani Gounder & Jeffrey Greeley & Guanghui Zhang & Jeffre, 2021. "Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Middleton, Richard S. & Gupta, Rajan & Hyman, Jeffrey D. & Viswanathan, Hari S., 2017. "The shale gas revolution: Barriers, sustainability, and emerging opportunities," Applied Energy, Elsevier, vol. 199(C), pages 88-95.
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    1. Xiaowen Chen & Xuetao Qin & Yueyue Jiao & Mi Peng & Jiangyong Diao & Pengju Ren & Chengyu Li & Dequan Xiao & Xiaodong Wen & Zheng Jiang & Ning Wang & Xiangbin Cai & Hongyang Liu & Ding Ma, 2023. "Structure-dependence and metal-dependence on atomically dispersed Ir catalysts for efficient n-butane dehydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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