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Life Cycle Assessment of Biochar versus Metal Catalysts Used in Syngas Cleaning

Author

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  • Robert S. Frazier

    (Biosystems and Agricultural Engineering, Oklahoma State University, 212 Ag Hall, Stillwater, OK 74074, USA)

  • Enze Jin

    (Biosystems and Agricultural Engineering, Oklahoma State University, 212 Ag Hall, Stillwater, OK 74074, USA)

  • Ajay Kumar

    (Biosystems and Agricultural Engineering, Oklahoma State University, 212 Ag Hall, Stillwater, OK 74074, USA)

Abstract

Biomass gasification has the potential to produce renewable fuels, chemicals and power at large utility scale facilities. In these plants catalysts would likely be used to reform and clean the generated biomass syngas. Traditional catalysts are made from transition metals, while catalysts made from biochar are being studied. A life cycle assessment (LCA) study was performed to analyze the sustainability, via impact assessments, of producing a metal catalyst versus a dedicated biochar catalyst. The LCA results indicate that biochar has a 93% reduction in greenhouse gas (GHG) emissions and requires 95.7% less energy than the metal catalyst to produce. The study also estimated that biochar production would also have fewer impacts on human health (e.g., carcinogens and respiratory impacts) than the production of a metal catalyst. The possible disadvantage of biochar production in the ecosystem quality is due mostly to its impacts on agricultural land occupation. Sensitivity analysis was carried out to assess environmental impacts of variability in the two production systems. In the metal catalyst manufacture, the extraction and production of nickel (Ni) had significant negative effects on the environmental impacts. For biochar production, low moisture content (MC, 9%) and high yield type (8 tons/acre) switchgrass appeared more sustainable.

Suggested Citation

  • Robert S. Frazier & Enze Jin & Ajay Kumar, 2015. "Life Cycle Assessment of Biochar versus Metal Catalysts Used in Syngas Cleaning," Energies, MDPI, vol. 8(1), pages 1-24, January.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:1:p:621-644:d:44770
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    References listed on IDEAS

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    Cited by:

    1. Wang, Xiaoliu & Yang, Meng & Zhu, Xiaonan & Zhu, Lingjun & Wang, Shurong, 2020. "Experimental study and life cycle assessment of CO2 methanation over biochar supported catalysts," Applied Energy, Elsevier, vol. 280(C).
    2. Sara Rajabi Hamedani & Tom Kuppens & Robert Malina & Enrico Bocci & Andrea Colantoni & Mauro Villarini, 2019. "Life Cycle Assessment and Environmental Valuation of Biochar Production: Two Case Studies in Belgium," Energies, MDPI, vol. 12(11), pages 1-21, June.
    3. Freire Ordóñez, Diego & Shah, Nilay & Guillén-Gosálbez, Gonzalo, 2021. "Economic and full environmental assessment of electrofuels via electrolysis and co-electrolysis considering externalities," Applied Energy, Elsevier, vol. 286(C).
    4. Ravenni, G. & Elhami, O.H. & Ahrenfeldt, J. & Henriksen, U.B. & Neubauer, Y., 2019. "Adsorption and decomposition of tar model compounds over the surface of gasification char and active carbon within the temperature range 250–800 °C," Applied Energy, Elsevier, vol. 241(C), pages 139-151.
    5. Ali Abdelaal & Vittoria Benedetti & Audrey Villot & Francesco Patuzzi & Claire Gerente & Marco Baratieri, 2023. "Innovative Pathways for the Valorization of Biomass Gasification Char: A Systematic Review," Energies, MDPI, vol. 16(10), pages 1-24, May.
    6. Bamdad, Hanieh & Hawboldt, Kelly & MacQuarrie, Stephanie, 2018. "A review on common adsorbents for acid gases removal: Focus on biochar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1705-1720.

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