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Biodiesel NOx penalty and control measures - a review

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  • Thangaraja, J.
  • Anand, K.
  • Mehta, Pramod S.

Abstract

Biodiesel fuels comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats serve as a potential alternative to fossil diesel. The biodiesel fueled engine does not require any major hardware modifications in the existing configuration. Also, the uses of biodiesel in compression ignition engines are found to significantly lower soot emissions. Thus, the conventional nitric oxide-soot trade-off problem narrows down to a unidirectional control of nitric oxide emissions which are generally known to increase with several candidate biodiesel fuels. The formation of oxides of nitrogen (NOx) from biodiesel fuel is dependent on both fuel and engine characteristics. The present work reviews the effect of biodiesel fuel composition and properties on NOx emissions emanating from biodiesel fueled engines and describes fuel modifications and engine tuning measures for their mitigation. The other outcomes of biodiesel NOx control measures in terms of engine performance and emission changes are also highlighted and the best possible ways for achieving biodiesel-NOx neutrality are outlined.

Suggested Citation

  • Thangaraja, J. & Anand, K. & Mehta, Pramod S., 2016. "Biodiesel NOx penalty and control measures - a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 1-24.
  • Handle: RePEc:eee:rensus:v:61:y:2016:i:c:p:1-24
    DOI: 10.1016/j.rser.2016.03.017
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    8. Rajaeifar, Mohammad Ali & Tabatabaei, Meisam & Aghbashlo, Mortaza & Nizami, Abdul-Sattar & Heidrich, Oliver, 2019. "Emissions from urban bus fleets running on biodiesel blends under real-world operating conditions: Implications for designing future case studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 276-292.
    9. Thangamani, Saravanakumar & Sundaresan, Sathya Narayanan & Kannappan S., Subbu & Barawkar, Viraj Tatyasaheb & Jeyaseelan, Thangaraja, 2021. "Impact of biodiesel and diesel blends on the fuel filter: A combined experimental and simulation study," Energy, Elsevier, vol. 227(C).
    10. Gowrishankar, Sudarshan & Krishnasamy, Anand, 2023. "Emulsification – A promising approach to improve performance and reduce exhaust emissions of a biodiesel fuelled light-duty diesel engine," Energy, Elsevier, vol. 263(PC).
    11. Rajkumar, Sundararajan & Das, Arnab & Thangaraja, Jeyaseelan, 2022. "Integration of artificial neural network, multi-objective genetic algorithm and phenomenological combustion modelling for effective operation of biodiesel blends in an automotive engine," Energy, Elsevier, vol. 239(PA).
    12. Doppalapudi, A.T. & Azad, A.K. & Khan, M.M.K., 2023. "Advanced strategies to reduce harmful nitrogen-oxide emissions from biodiesel fueled engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 174(C).
    13. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    14. Ağbulut, Ümit & Yeşilyurt, Murat Kadir & Sarıdemir, Suat, 2021. "Wastes to energy: Improving the poor properties of waste tire pyrolysis oil with waste cooking oil methyl ester and waste fusel alcohol – A detailed assessment on the combustion, emission, and perform," Energy, Elsevier, vol. 222(C).

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