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Developments in in-situ (trans) esterification for biodiesel production: A critical review

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  • Go, Alchris Woo
  • Sutanto, Sylviana
  • Ong, Lu Ki
  • Tran-Nguyen, Phuong Lan
  • Ismadji, Suryadi
  • Ju, Yi-Hsu

Abstract

Biodiesel is a biofuel used as an alternative for petroleum diesel. The main obstacle in the widespread use of biodiesel lies mainly on its cost and current state of the technology to process a wide array of feedstock. The cost of biodiesel production is still high compared to that of petroleum based diesel fuel. The decrease of production cost can be achieved through the utilization of cheap, low quality feedstock and the development of simpler production process. In-situ (trans) esterification (ISTE) is an alternative route in synthesizing or producing biodiesel. ISTE involves lesser steps as it eliminates the need for lipid or oil extraction prior to (trans)esterification. A detailed comparison of the various strategies, mechanism involved and technologies developed since 1985 on ISTE processes is described in this review. This review tackles several technological gaps needing to be bridged and addressed in future studies. Furthermore, future prospects and possible developments in ISTE is also looked into.

Suggested Citation

  • Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    • Handle: RePEc:eee:rensus:v:60:y:2016:i:c:p:284-305
    DOI: 10.1016/j.rser.2016.01.070
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    2. Te, Kezia Gaile D. & Go, Alchris Woo & Wang, Hanneh Jonna D. & Guevarra, Reinell G. & Cabatingan, Luis K. & Tabañag, Ian Dominic F. & Angkawijaya, Artik Elisa & Ju, Yi-Hsu, 2020. "Extraction of lipids from post-hydrolysis copra cake with hexane as solvent: Kinetic and equilibrium data," Renewable Energy, Elsevier, vol. 158(C), pages 311-323.
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    7. Rastogi, Rajesh P. & Pandey, Ashok & Larroche, Christian & Madamwar, Datta, 2018. "Algal Green Energy – R&D and technological perspectives for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2946-2969.
    8. Quijote, Kristelle L. & Go, Alchris Woo & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Gunarto, Chintya & Zullaikah, Siti, 2023. "Non-isothermal in-situ (trans)esterification of lipids in pre-functionalized and lipid-dense post-hydrolysis spent coffee grounds with subcritical methanol at low subcritical condition," Renewable Energy, Elsevier, vol. 206(C), pages 111-124.
    9. Zimmerman, William B. & Kokoo, Rungrote, 2018. "Esterification for biodiesel production with a phantom catalyst: Bubble mediated reactive distillation," Applied Energy, Elsevier, vol. 221(C), pages 28-40.
    10. Wong, Wan-Ying & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Lam, Man-Kee & Tan, Inn-Shi & Chen, Wei-Hsin, 2023. "A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    11. Go, Alchris Woo & Quijote, Kristelle L. & Alivio, Roxanne Kathlyn O. & Ju, Yi-Hsu & Gunarto, Chintya & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Yuliana, Maria, 2022. "Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol," Renewable Energy, Elsevier, vol. 189(C), pages 13-24.
    12. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    13. Felix, Charles & Ubando, Aristotle & Madrazo, Cynthia & Gue, Ivan Henderson & Sutanto, Sylviana & Tran-Nguyen, Phuong Lan & Go, Alchris Woo & Ju, Yi-Hsu & Culaba, Alvin & Chang, Jo-Shu & Chen, Wei-Hsi, 2019. "Non-catalytic in-situ (trans) esterification of lipids in wet microalgae Chlorella vulgaris under subcritical conditions for the synthesis of fatty acid methyl esters," Applied Energy, Elsevier, vol. 248(C), pages 526-537.
    14. Migle Santaraite & Egle Sendzikiene & Violeta Makareviciene & Kiril Kazancev, 2020. "Biodiesel Production by Lipase-Catalyzed in Situ Transesterification of Rapeseed Oil Containing a High Free Fatty Acid Content with Ethanol in Diesel Fuel Media," Energies, MDPI, vol. 13(10), pages 1-12, May.
    15. Koytsoumpa, E.I. & Magiri – Skouloudi, D. & Karellas, S. & Kakaras, E., 2021. "Bioenergy with carbon capture and utilization: A review on the potential deployment towards a European circular bioeconomy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).

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