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Influence of temperature on organic structure of biomass pyrolysis products

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  • Xiao, Ruirui
  • Yang, Wei

Abstract

Biomass pyrolysis experiments were performed in a tubular reactor at different temperatures, the effects of which on organic structure of semi-char and tar had been investigated. Fourier-transform infrared (FTIR) analysis was conducted by a Nicolet 6700 FTIR spectrometer. The tar components at different temperatures were analyzed by GC/MS. It was observed that pyrolysis of biomass mainly occurs in the temperature range of 300–600°C. A high temperature favored the production of gases. The yield of semi-char and the contained organic functional groups(CO, CC, C–H, C–O and OH) decreases significantly with the increasing final temperature. The tar yield passes through a maximum at about 500°C. The organic functional groups in tar were stable but the transmittance of these groups decreased with the increasing final temperature.

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  • Xiao, Ruirui & Yang, Wei, 2013. "Influence of temperature on organic structure of biomass pyrolysis products," Renewable Energy, Elsevier, vol. 50(C), pages 136-141.
    • Handle: RePEc:eee:renene:v:50:y:2013:i:c:p:136-141
    DOI: 10.1016/j.renene.2012.06.028
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    1. Xiao, Ruirui & Chen, Xueli & Wang, Fuchen & Yu, Guangsuo, 2011. "The physicochemical properties of different biomass ashes at different ashing temperature," Renewable Energy, Elsevier, vol. 36(1), pages 244-249.
    2. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
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