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Producing petrochemicals from catalytic fast pyrolysis of corn fermentation residual by-products generated from citric acid production

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  • Li, Xiangyu
  • Li, Guangyu
  • Li, Jian
  • Yu, Yanqing
  • Feng, Yu
  • Chen, Qun
  • Komarneni, Sridhar
  • Wang, Yujue

Abstract

Citric acid production from corn fermentation generates significant amounts of fermentation residual by-products that need to be disposed of. To valorize the corn fermentation residues (CFRs), this study investigated catalytic fast pyrolysis (CFP) of CFRs alone or with low-density polyethylene (LDPE) to produce petrochemicals (aromatic hydrocarbons and olefins) using ZSM-5 zeolites as the catalyst. Results indicate that ZSM-5 zeolites decreased the activation energy of CFRs thermal decomposition by ∼15%. In addition, the introduction of ZSM-5 dramatically changed the compositions of condensable products from predominantly oxygenated compounds (e.g., furans, ketones, and acids) in non-CFP of CFRs to essentially aromatic hydrocarbons (e.g., benzene, toluene, and xylenes (BTX)) in CFP. Petrochemical yield of 30.4 C% was obtained in CFP of CFRs alone, and further improved to 40.3–52.1 C% when 10–33.3 wt.% LDPE was co-fed with CFRs in CFP. Important primary petrochemicals (BTX, ethylene and propylene) constituted the predominant fractions (66.8–71.1%) of the petrochemical products from CFP of CFRs alone and co-feed CFP with LDPE. These results indicate that CFRs are an attractive biomass feedstock for the production of high value-added petrochemicals by CFP process.

Suggested Citation

  • Li, Xiangyu & Li, Guangyu & Li, Jian & Yu, Yanqing & Feng, Yu & Chen, Qun & Komarneni, Sridhar & Wang, Yujue, 2016. "Producing petrochemicals from catalytic fast pyrolysis of corn fermentation residual by-products generated from citric acid production," Renewable Energy, Elsevier, vol. 89(C), pages 331-338.
    • Handle: RePEc:eee:renene:v:89:y:2016:i:c:p:331-338
    DOI: 10.1016/j.renene.2015.11.077
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    References listed on IDEAS

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    1. Lu, Ke-Miao & Lee, Wen-Jhy & Chen, Wei-Hsin & Lin, Ta-Chang, 2013. "Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends," Applied Energy, Elsevier, vol. 105(C), pages 57-65.
    2. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    3. Shadangi, Krushna Prasad & Mohanty, Kaustubha, 2014. "Kinetic study and thermal analysis of the pyrolysis of non-edible oilseed powders by thermogravimetric and differential scanning calorimetric analysis," Renewable Energy, Elsevier, vol. 63(C), pages 337-344.
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    1. Jiang, Jiaxin & Li, Xiaohua & Shao, Shanshan & Sun, Jiayuan & Yu, Zining & Cai, Yixi, 2023. "Experimental study on catalytic pyrolysis of rape straw with the active cathode material of spent lithium-ion batteries and HZSM-5 as the tandem catalysts," Renewable Energy, Elsevier, vol. 204(C), pages 803-811.

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