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Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction

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  • Simões, S.S.
  • Ribeiro, J.S.
  • Celante, D.
  • Brondani, L.N.
  • Castilhos, F.

Abstract

This study aimed the investigation of a potential heterogeneous catalyst for the interesterification reaction for soybean biodiesel production. Different types of catalysts (Y Zeolite, MgO, Nb2O5 and mixed oxides) were tested in this work. Ca–Mg–Al mixed oxide with 40% wt. Ca was the more suitable catalyst for interesterification reaction. Effects of temperature, catalyst content and methyl acetate to oil molar ratio on product yields were investigated through kinetic experiments. Kinetic behavior of intermediate compounds was also assessed. The best experimental condition was 325 °C, 40:1 methyl acetate/oil molar ratio and 5% wt. of catalyst/oil, with a global yield of 68.55% reached in 80 min with pressure ranged between 5 and 10 MPa. A catalyst reusing test was carried out in this condition. The reaction could be performed for at least three times with the same initial catalyst without a significant activity decay.

Suggested Citation

  • Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:719-726
    DOI: 10.1016/j.renene.2019.07.023
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    Cited by:

    1. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    2. Brondani, L.N. & Ribeiro, J.S. & Castilhos, F., 2020. "A new kinetic model for simultaneous interesterification and esterification reactions from methyl acetate and highly acidic oil," Renewable Energy, Elsevier, vol. 156(C), pages 579-590.
    3. Reza Nageubri Balfas & Azhari Muhammad Syam & Muhammad Muhammad & Adi Setiawan & Herman Fithra, 2024. "Characteristics of Biodiesel Produced from Crude Palm Oil through Non-Alcohol Synthesis Route Using Dimethyl Carbonate and Immobilized Eco-Enzyme Catalyst," Energies, MDPI, vol. 17(7), pages 1-16, March.
    4. Wong, Wan-Ying & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Lam, Man-Kee & Tan, Inn-Shi & Chen, Wei-Hsin, 2023. "A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).

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