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Numerical study of carbon monoxide poisoning effect on high temperature PEMFCs based on an elementary reaction kinetics coupled electrochemical reaction model

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  • Xu, Jiawei
  • Xiao, Shengying
  • Xu, Xinrui
  • Xu, Xinhai

Abstract

High-temperature proton exchange membrane fuel cells have received lots of attention due to their high tolerance of impurities in the fuel gas. Many researchers have conducted experimental and numerical investigations to study the influence of carbon monoxide on performance of the high-temperature proton exchange membrane fuel cell. However, most numerical models use an empirical formula to consider the effect of adsorption and desorption of hydrogen and carbon monoxide. To more accurately study the influence mechanism of carbon monoxide as an impurity, a novel three-dimensional non-isothermal model considering elementary reactions of hydrogen and carbon monoxide for high-temperature proton exchange membrane fuel cells is developed in this study. The elementary reaction kinetics of the anodic catalytic layer adopts a six-step global reaction, and the adsorption processes, desorption processes, as well as electrochemical reactions are taken into account. This model is able to accurately predict the steady polarization curve of a high-temperature proton exchange membrane fuel cell fed by hydrogen containing different amounts of carbon monoxide. The sensitivities of elementary reaction rates in the voltage range of 0.4–0.9 V for the fuel cell fed by pure hydrogen or a mixture of hydrogen and carbon monoxide are analyzed. The rate-determination step is studied at different voltages. In addition, the distributions of gaseous species, surface species and reaction rates of all elementary reactions along different directions of the anode catalytic layer are presented. Finally, the influences of carbon monoxide content in the fuel gas and the operating temperature of a high-temperature proton exchange membrane fuel cell fed by a mixture of hydrogen and carbon monoxide are numerically studied.

Suggested Citation

  • Xu, Jiawei & Xiao, Shengying & Xu, Xinrui & Xu, Xinhai, 2022. "Numerical study of carbon monoxide poisoning effect on high temperature PEMFCs based on an elementary reaction kinetics coupled electrochemical reaction model," Applied Energy, Elsevier, vol. 318(C).
    • Handle: RePEc:eee:appene:v:318:y:2022:i:c:s0306261922005797
    DOI: 10.1016/j.apenergy.2022.119214
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    References listed on IDEAS

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    1. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    2. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    3. Ribeirinha, P. & Abdollahzadeh, M. & Sousa, J.M. & Boaventura, M. & Mendes, A., 2017. "Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell," Applied Energy, Elsevier, vol. 202(C), pages 6-19.
    4. Jiao, Kui & Zhou, Yibo & Du, Qing & Yin, Yan & Yu, Shuhai & Li, Xianguo, 2013. "Numerical simulations of carbon monoxide poisoning in high temperature proton exchange membrane fuel cells with various flow channel designs," Applied Energy, Elsevier, vol. 104(C), pages 21-41.
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    1. Xu, Jiawei & Wu, Yuhua & Xiao, Shengying & Wang, Yifei & Xu, Xinhai, 2023. "Synergic effect investigation of carbon monoxide and other compositions on the high temperature proton exchange membrane fuel cell," Renewable Energy, Elsevier, vol. 211(C), pages 669-680.
    2. Guo, Xinru & Guo, Yumin & Wang, Jiangfeng & Meng, Xin & Deng, Bohao & Wu, Weifeng & Zhao, Pan, 2023. "Thermodynamic analysis of a novel combined heating and power system based on low temperature solid oxide fuel cell (LT-SOFC) and high temperature proton exchange membrane fuel cell (HT-PEMFC)," Energy, Elsevier, vol. 284(C).

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